A Cationic Calcium Hydride Cluster Stabilized by Cyclen-Derived Macrocyclic N,N,N,N Ligands

A Cationic Calcium Hydride Cluster Stabilized by Cyclen-Derived Macrocyclic N,N,N,N Ligands

Cationic calcium hydride complexes with a [Ca3(μ3‐H)2] core were prepared from different organocalcium precursors and Ph2SiH2. The hydride complexes were found to be active in the catalytic hydrosilylation and hydrogenation of 1,1‐diphenylethene.

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Veröffentlicht in:Angewandte Chemie International Edition 2012-04, Vol.51 (18), p.4452-4455
Hauptverfasser: Jochmann, Phillip, Davin, Julien P., Spaniol, Thomas P., Maron, Laurent, Okuda, Jun
Format: Artikel
Sprache:eng
Schlagworte:
alkaline earth metals
calcium
homogeneous catalysis
hydrides
hydrogen storage
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Zusammenfassung:Cationic calcium hydride complexes with a [Ca3(μ3‐H)2] core were prepared from different organocalcium precursors and Ph2SiH2. The hydride complexes were found to be active in the catalytic hydrosilylation and hydrogenation of 1,1‐diphenylethene.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201200690