Effects of post-deposition anneal on the electrical properties of Si3N4 gate dielectric

The effects of postdeposition anneal of chemical vapor deposited silicon nitride are studied. The Si 3 N 4 films were in situ annealed in either H 2 (2%)/O 2 at 950/spl deg/C or N 2 O at 950/spl deg/C in a rapid thermal oxidation system. It is found that an interfacial oxide was grown at the Si 3 N...

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Veröffentlicht in:IEEE electron device letters 2002-03, Vol.23 (3), p.124-126
Hauptverfasser: Lin, W.H., Pey, K.L., Dong, Z., Choi, S.Y.-M., Zhou, M.S., Ang, T.C., Ang, C.H., Lau, W.S., Ye, J.H.
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container_end_page 126
container_issue 3
container_start_page 124
container_title IEEE electron device letters
container_volume 23
creator Lin, W.H.
Pey, K.L.
Dong, Z.
Choi, S.Y.-M.
Zhou, M.S.
Ang, T.C.
Ang, C.H.
Lau, W.S.
Ye, J.H.
description The effects of postdeposition anneal of chemical vapor deposited silicon nitride are studied. The Si 3 N 4 films were in situ annealed in either H 2 (2%)/O 2 at 950/spl deg/C or N 2 O at 950/spl deg/C in a rapid thermal oxidation system. It is found that an interfacial oxide was grown at the Si 3 N 4 /Si interface by both postdeposition anneal conditions. This was confirmed by thickness measurement and X-ray photoelectronic spectroscopy (XPS) analysis. The devices with H 2 (2%)/O 2 anneal exhibit a lower gate leakage current and improved reliability compared to that of N 2 O anneal. This improvement is attributed to a greater efficiency of generating atomic oxygen in the presence of a small amount of hydrogen, leading to the elimination of structural defects in the as-deposited Si 3 N 4 film by the atomic oxygen. Good drivability is also demonstrated on a 0.12 μm n-MOSFET device.
doi_str_mv 10.1109/55.988812
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subjects Chemicals
Hydrogen
Leakage current
MOSFET circuits
Oxidation
Rapid thermal annealing
Semiconductor films
Silicon
Spectroscopy
Thickness measurement
title Effects of post-deposition anneal on the electrical properties of Si3N4 gate dielectric
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