Experimental study of the dehydration of 10-Å phase, with implications for its H2O content and stability in subducted lithosphere

The 10-Å phase (TAP) is a hydrous magnesium silicate that forms from the reaction of talc with H 2 O at high pressures. Its high-pressure, low-temperature stability means that it could be a storage site for H 2 O in subduction zones. We have determined the position of the TAP dehydration reaction, TAP = enstatite + coesite + H 2 O, in phase-equilibrium experiments from 5.0 to 7.1 GPa. Because previous studies had suggested that the composition of TAP is a function of synthesis duration, we used a TAP sample that was synthesised for 392 h. Over the pressure interval of our experiments, the dehydration reaction is isothermal, occurring at a temperature of ~690°C. It is coincident, within experimental uncertainty, with the position of the dehydration reaction of TAP synthesised in short experiments (up to 46 h). Above 7.5 GPa, TAP breaks down to enstatite + stishovite + H 2 O. This reaction has a negative d P /d T and terminates at an invariant point involving the 3.65-Å phase at ~9.5 GPa, 500°C. The zero volume change implied by the isothermal reaction TAP = enstatite + coesite + H 2 O was used to calculate the interlayer H 2 O content of TAP along the reaction. A best-fit H 2 O content of 1 H 2 O pfu was obtained. This H 2 O content is independent of TAP synthesis conditions, suggesting that variations in previously measured H 2 O contents of TAP occur during quenching and decompression of the samples. The stability of TAP in the Earth is probably limited to cold subduction zones, but in these, it could persist to 300 km depth.