Oxidation of cobalt(II) with air oxygen in aqueous ethylenediamine solutions

Oxidation of aqueous Co(NO^sub 3^)^sub 2^-ethylenediamine (En) solutions with air oxygen was investigated at 20 °C and pH 5.2-7.0, with and without mechanical stirring, by measuring the Co^sup II^ concentration, pH and redox potential on an Au electrode. In most cases, the oxidation rate was proportional to the concentration of CoEn^sup 2+^^sub n^ (n = 2, 3) complexes, and the influence of the solution pH on the rate of reaction was accounted for by the pH dependence of the Co^sup II^ complex distribution. It was found that sulphate inhibits and bromide accelerates the oxidation process. Possible oxidation routes are discussed. The oxidation process is limited to some extent by O^sub 2^ transport from the air to the bulk solution.[PUBLICATION ABSTRACT]