Extraction of nickel from nickel alloy by carbonylation

Carbonylation refining technology has been used to extract nickel from nickel alloy. Before carbonylation, roasting and size reduction is used as a pre-treatment method, and re-activation with H 2 is needed. During carbonylation, the addition of H 2 S helps to activate the nickel surface and improve...

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Veröffentlicht in:Transition metal chemistry (Weinheim) 2009-04, Vol.34 (3), p.313-316
Hauptverfasser: Wang, Duodong, Chen, Ailiang, Zhao, Zhongwei, Huo, Guangsheng
Format: Artikel
Sprache:eng
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Zusammenfassung:Carbonylation refining technology has been used to extract nickel from nickel alloy. Before carbonylation, roasting and size reduction is used as a pre-treatment method, and re-activation with H 2 is needed. During carbonylation, the addition of H 2 S helps to activate the nickel surface and improve the extraction rate. The supply of H 2 S does not necessarily need to be continuous. The optimum parameters for extraction of nickel are a carbonylation temperature of 70 °C, pressure of 10 bar, flow rate of 0.25–0.35 L/min and mixture of CO and H 2 S as carbonylation agent. The best extraction rate of nickel can reach 99%.
ISSN:0340-4285
1572-901X
DOI:10.1007/s11243-009-9196-x