Extraction of nickel from nickel alloy by carbonylation
Carbonylation refining technology has been used to extract nickel from nickel alloy. Before carbonylation, roasting and size reduction is used as a pre-treatment method, and re-activation with H 2 is needed. During carbonylation, the addition of H 2 S helps to activate the nickel surface and improve...
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Veröffentlicht in: | Transition metal chemistry (Weinheim) 2009-04, Vol.34 (3), p.313-316 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Carbonylation refining technology has been used to extract nickel from nickel alloy. Before carbonylation, roasting and size reduction is used as a pre-treatment method, and re-activation with H
2
is needed. During carbonylation, the addition of H
2
S helps to activate the nickel surface and improve the extraction rate. The supply of H
2
S does not necessarily need to be continuous. The optimum parameters for extraction of nickel are a carbonylation temperature of 70 °C, pressure of 10 bar, flow rate of 0.25–0.35 L/min and mixture of CO and H
2
S as carbonylation agent. The best extraction rate of nickel can reach 99%. |
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ISSN: | 0340-4285 1572-901X |
DOI: | 10.1007/s11243-009-9196-x |