Structure of Copper(II) Complexes with 2-[2-Hydroxy-Phenil]-4,4-Diphenyl-1,2-Dihydro- 4H-3,1-Benzoxazine in Chloroform

Structure of Copper(II) Complexes with 2-[2-Hydroxy-Phenil]-4,4-Diphenyl-1,2-Dihydro- 4H-3,1-Benzoxazine in Chloroform

Electronic spectra of copper(II) complexes CuL2 and Cu2L2Ac2 (L-2-[2-hydroxy-phenil]-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine, Ac –CH3COO-) (L) in chloroform are studied. It is shown that complex Cul2 has rhombic bipyramid polyhedron and complex Cu2L2Ac2 has tetragonal pyramidal polyhedron of cop...

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Veröffentlicht in:Advances in Physical Chemistry 2009-01, Vol.2009 (2009), p.68-71
Hauptverfasser: Bolotin, S. N., Isaeva, E. L., Shamsutdinova, M. H., Pushkareva, K. S., Bukov, N. N.
Format: Artikel
Sprache:eng
Schlagworte:
Colleges & universities
Crystal structure
Spectrum analysis
Symmetry
Vibration
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Zusammenfassung:Electronic spectra of copper(II) complexes CuL2 and Cu2L2Ac2 (L-2-[2-hydroxy-phenil]-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine, Ac –CH3COO-) (L) in chloroform are studied. It is shown that complex Cul2 has rhombic bipyramid polyhedron and complex Cu2L2Ac2 has tetragonal pyramidal polyhedron of copper ion. Results of definition of geometry for complexes in solution correlate with structure of solid complexes.
ISSN:1687-7985
1687-7993
DOI:10.1155/2009/365949