Electrochemical sensor based on Prussian blue nanorods and gold nanochains for the determination of H2O2

In this paper, a novel electrochemical sensor for the detection of H 2 O 2 was proposed based on gold nanochains and prussian blue nanorods (PB@MWCNTs), which were synthesized with multiwall carbon nanotubes (MWCNTs) as a template. With the introduction of MWCNTs and the gold nanochains, the propose...

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Veröffentlicht in:European food research & technology 2011, Vol.232 (1), p.87-95
Hauptverfasser: Chen, Shihong, Ma, Liping, Yuan, Ruo, Chai, Yaqin, Xiang, Yun, Wang, Chengyan
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Sprache:eng
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Zusammenfassung:In this paper, a novel electrochemical sensor for the detection of H 2 O 2 was proposed based on gold nanochains and prussian blue nanorods (PB@MWCNTs), which were synthesized with multiwall carbon nanotubes (MWCNTs) as a template. With the introduction of MWCNTs and the gold nanochains, the proposed system shows synergy among the Prussian blue (PB), MWCNTs, and the gold nanochains, which amplifies the H 2 O 2 sensitivity greatly. A linear range from 1.75 × 10 −6 to 1.14 × 10 −3  M with a detection limit of 0.5 × 10 −6  M ( S / N  = 3) and a high sensitivity 300 μA mM −1  cm −2 for H 2 O 2 detection is obtained. Moreover, the sensor exhibits good repeatability and stability.
ISSN:1438-2377
1438-2385
DOI:10.1007/s00217-010-1364-x