Characterization of Exhaust Particulates from a Dual Fuel Engine by TGA, XPS, and Raman Techniques

Particulate matter (PM) emitted from a dual fuel engine is characterized using thermogravimetry, X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. Thermogravimetric analysis (TGA) provides the mass fractions of elemental carbon and volatile materials in PM; XPS provides the possible chemical compositions in the topmost layer of PM surface and Raman analysis provides the possible structure of the carbon presented in PM. Dual fuel engine uses both liquid (diesel) and gaseous fuels simultaneously to produce mechanical power and can be switched to only diesel fueling under load. The dual fuel engine is operated with natural gas and simulated biogases (laboratory prepared) and results are compared between the dual fueling and diesel fueling under the same engine operating conditions. Significantly higher volatile fractions in PM are obtained for dual fueling compared to diesel fueling complementing the gravimetric results. The maximum contribution of the graphitic carbon or aliphatic carbon such as hydrocarbons and paraffins (C═C or C─C) are found in the topmost atomic layers of both the diesel and dual fuel PM samples. The other chemical states are found to be the carbon-oxygen functional groups indicating significant oxidation behavior in the PM surface. Lesser aromatic content is noticed in the case of dual fuel PM than diesel PM. The carbon in dual fuel PM is found to be more amorphous compared to diesel PM. These characterizations provide us new information how the PM from a diesel engine can be different from that from a dual fuel engine.