The stable isotope geochemical characteristics of dissolved inorganic carbon in northern South China Sea

The isotopic composition of dissolved inorganic carbon （DIC） in marine and estuarine environments has been studied in some detail because of its role in determining the isotopic composition of inorganic/organic matter and its applications to the study of various natural processes. The δ^13DIC values of sea water are controlled by the sources and sinks of carbon and the results from isotope fractionation among solid, dissolved and gaseous phases. In this paper, based on the description of the stable isotope geochemical characteristics of dissolved inorganic carbon in northern South China Sea, the following conclusions were drawn： 1） the δ^13DIC values of natural waters are controlled by the sources and sinks of carbon and the results from isotope fractionation among solid, dissolved and gaseous phases. And the low seawater δ^13DIC values of northern South China Sea are accompanied by a low level of sea primary productivity in this region; 2） according to the parameter relationship （δ^13DIC-1.1 PO4） between δ^13DIC and PO4, it is indicated that northern South China Sea is the source of atmospheric CO2; and 3） nitrogen （N） and phosphorus （P） are the elements which are the basis for phytoplankton growth. Based on the analysis of seawater δ^13DIC values and PO4 and NO3＋NO2 concentrations, our data show that N is a limiting nutrient in northern South China Sea.