Oriented Titanium‐MOF Membrane for Hydrogen Purification

Precise hydrogen sorting from purge gas (H2/N2) and coke gas (H2/CH4), commonly carried out by cryogenic distillation, still suffers from low separation efficiency, high energy consumption, and considerable capital cost. Though still in its infancy, membrane technology offers a potential to achieve more efficient hydrogen purification. In this study, an optimum separation of hydrogen towards both methane and nitrogen via a kinetically‐driven mechanism is realized through preferred orientation control of a MOF membrane. Relying on the 0.3 nm‐sized window aligned vertical to the substrate, b‐oriented Ti‐MOF membrane exhibits ultra‐high hydrogen selectivity, surpassing the upper bound limit of separating H2/N2 and H2/CH4 gas pairs attained so far by inorganic membranes. This spectacular selectivity is combined with a high H2 permeability owing to the synergistic effect of the 1 nm‐sized MOF channel. Through precise orientation control, b‐oriented MIP‐177‐LT membranes exhibit superior performances towards hydrogen purification relying on the 0.3 nm‐sized window aligned vertical to the substrate. At the same time, due to the synergistic effect of 1 nm‐sized MOF channel, this spectacular selectivity is combined with a high H2 permeability.