A Constrained Geometry Fluorenyl Amido Magnesium Catalyst for Amine‐Borane Dehydrocoupling

A fluorenyl amido constrained geometry magnesium complex is described, which was obtained by deprotonation of the corresponding neutral ligand system with dibutyl magnesium. Its structure was determined by SC‐XRD and it was shown to be a potent catalyst for amine‐borane dehydrogenation/dehydrocoupli...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2024-11, Vol.650 (23), p.n/a
Hauptverfasser: Lambert, Jessica, Morgenstern, Bernd, Schäfer, André
Format: Artikel
Sprache:eng
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Zusammenfassung:A fluorenyl amido constrained geometry magnesium complex is described, which was obtained by deprotonation of the corresponding neutral ligand system with dibutyl magnesium. Its structure was determined by SC‐XRD and it was shown to be a potent catalyst for amine‐borane dehydrogenation/dehydrocoupling.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.202400136