Eco-friendly preparation of V2O5/g-C3N4 nanosheets as efficient high-performance supercapacitor electrode material
V 2 O 5 /g-C 3 N 4 composites including g-C 3 N 4 nanosheet carbon have been widely studied to solve challenges such as poor intrinsic electrical conductivity, substantial irreversibility, and exceptional stability. A time-saving hydrothermal autoclave synthesis method was used to fuse V 2 O 5 /g-C...
Gespeichert in:
Veröffentlicht in: | Ionics 2024-11, Vol.30 (11), p.7489-7501 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | V
2
O
5
/g-C
3
N
4
composites including g-C
3
N
4
nanosheet carbon have been widely studied to solve challenges such as poor intrinsic electrical conductivity, substantial irreversibility, and exceptional stability. A time-saving hydrothermal autoclave synthesis method was used to fuse V
2
O
5
/g-C
3
N
4
composite strands. V
2
O
5
/g-C
3
N
4
composite is a hybrid nanoparticle with important properties for the electrode of a supercapacitor that has been studied and published. The phase structure, space group, and crystallite size of nanoparticles were determined using X-ray diffraction (XRD) peak examination. The resulting materials are analyzed using the Fourier transform infrared spectrometer (FTIR), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscope (HRTEM), Brunauer–Emmett–Teller (BET), and X-ray photoelectron spectroscopy (XPS). The average crystalline diameters of graphitic carbon nitride (g-C
3
N
4
), vanadium pentoxide (V
2
O
5
), and V
2
O
5
/g-C
3
N
4
composites are 28 nm, 16 nm, and 12 nm, respectively. FESEM determines the distribution of V
2
O
5
throughout the g-C₃N₄ nanosheets. XPS detects the elements present in the composite, confirming the presence of V, O, C, and N. The V
2
O
5
/g-C
3
N
4
composite provides insights into the surface chemistry and probable interactions between V₂O₅ and g-C₃N₄. V
2
O
5
/g-C
3
N
4
nanoparticles have a specific capacitance of 286.54 F/g and are estimated at 2 A/g using the galvanostatic charge–discharge technique, which provides superior stability even after 3000 charge/discharge cycles. Their remarkable performance is due to the synergistic impact of g-C
3
N
4
and V
2
O
5
/g-C
3
N
4
. Such outstanding results may open up new possibilities for these electrode materials in high-energy–density storage devices. The composites also showed high cycle stability due to the peculiar structure of the V
2
O
5
and synergy with g-C
3
N
4
. |
---|---|
ISSN: | 0947-7047 1862-0760 |
DOI: | 10.1007/s11581-024-05815-8 |