Copper(II) 2-(N-Tosylamino)benzaldehyde Benzoylhydrazone Complexes: Synthesis, Structures, Properties, and Biological Activity
A number of new copper(II) complexes of 2-( N -tosylamino)benzaldehyde benzoylhydrazone (H 2 L) CuLL n ( n = 1–6) with heterocyclic donor ligands (L 1 = 1-propyl-2-aminobenzimidazole, L 2 = 1‑hexyl-2-aminobenzimidazole, L 3 = 1-octyl-2-aminobenzimidazole, L 4 = 2,2'-bipyridine, L 5 = 1,10-phena...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2024-08, Vol.50 (8), p.543-556 |
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| creator | Chal’tsev, B. V. Burlov, A. S. Vlasenko, V. G. Koshchienko, Yu. V. Zubenko, A. A. Klimenko, A. I. Lazarenko, V. A. Mashchenko, S. A. Korshunova, E. V. Lifintseva, T. V. |
| description | A number of new copper(II) complexes of 2-(
N
-tosylamino)benzaldehyde benzoylhydrazone (H
2
L) CuLL
n
(
n
= 1–6) with heterocyclic donor ligands (L
1
= 1-propyl-2-aminobenzimidazole, L
2
= 1‑hexyl-2-aminobenzimidazole, L
3
= 1-octyl-2-aminobenzimidazole, L
4
= 2,2'-bipyridine, L
5
= 1,10-phenanthroline, and L
6
= 2-aminopyridine) is synthesized. The structures and compositions of the synthesized compounds are determined by elemental analysis,
1
Н NMR spectroscopy, IR spectroscopy, and magnetochemistry. The molecular structures of complexes CuLL
1,2,4−6
are determined by XRD (CIF files CCDC nos. 2341480 (CuLL
1
), 2341468 (CuLL
2
), 2341478 (CuLL
4
), 2341477 (CuLL
5
), and 2341479 (CuLL
6
)). The biological activity of the complexes is studied. The adducts with L
1
, L
2
, and L
6
exhibit a significantly higher anti-protist activity than chloroquine used as the reference compound. |
| doi_str_mv | 10.1134/S1070328424600438 |
| format | Article |
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N
-tosylamino)benzaldehyde benzoylhydrazone (H
2
L) CuLL
n
(
n
= 1–6) with heterocyclic donor ligands (L
1
= 1-propyl-2-aminobenzimidazole, L
2
= 1‑hexyl-2-aminobenzimidazole, L
3
= 1-octyl-2-aminobenzimidazole, L
4
= 2,2'-bipyridine, L
5
= 1,10-phenanthroline, and L
6
= 2-aminopyridine) is synthesized. The structures and compositions of the synthesized compounds are determined by elemental analysis,
1
Н NMR spectroscopy, IR spectroscopy, and magnetochemistry. The molecular structures of complexes CuLL
1,2,4−6
are determined by XRD (CIF files CCDC nos. 2341480 (CuLL
1
), 2341468 (CuLL
2
), 2341478 (CuLL
4
), 2341477 (CuLL
5
), and 2341479 (CuLL
6
)). The biological activity of the complexes is studied. The adducts with L
1
, L
2
, and L
6
exhibit a significantly higher anti-protist activity than chloroquine used as the reference compound.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328424600438</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adducts ; Aminobenzimidazole ; Benzaldehyde ; Biological activity ; Biological properties ; Chemical analysis ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Copper ; Infrared spectroscopy ; Inorganic Chemistry ; Magnetochemistry ; Molecular structure ; NMR spectroscopy ; Physical Chemistry</subject><ispartof>Russian journal of coordination chemistry, 2024-08, Vol.50 (8), p.543-556</ispartof><rights>Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 8, pp. 543–556. © Pleiades Publishing, Ltd., 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-e077b201cbecf88ef9c0f03803c10e8fd2c5be5a019d5c2965e273c7744cc8f23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328424600438$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328424600438$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Chal’tsev, B. V.</creatorcontrib><creatorcontrib>Burlov, A. S.</creatorcontrib><creatorcontrib>Vlasenko, V. G.</creatorcontrib><creatorcontrib>Koshchienko, Yu. V.</creatorcontrib><creatorcontrib>Zubenko, A. A.</creatorcontrib><creatorcontrib>Klimenko, A. I.</creatorcontrib><creatorcontrib>Lazarenko, V. A.</creatorcontrib><creatorcontrib>Mashchenko, S. A.</creatorcontrib><creatorcontrib>Korshunova, E. V.</creatorcontrib><creatorcontrib>Lifintseva, T. V.</creatorcontrib><title>Copper(II) 2-(N-Tosylamino)benzaldehyde Benzoylhydrazone Complexes: Synthesis, Structures, Properties, and Biological Activity</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>A number of new copper(II) complexes of 2-(
N
-tosylamino)benzaldehyde benzoylhydrazone (H
2
L) CuLL
n
(
n
= 1–6) with heterocyclic donor ligands (L
1
= 1-propyl-2-aminobenzimidazole, L
2
= 1‑hexyl-2-aminobenzimidazole, L
3
= 1-octyl-2-aminobenzimidazole, L
4
= 2,2'-bipyridine, L
5
= 1,10-phenanthroline, and L
6
= 2-aminopyridine) is synthesized. The structures and compositions of the synthesized compounds are determined by elemental analysis,
1
Н NMR spectroscopy, IR spectroscopy, and magnetochemistry. The molecular structures of complexes CuLL
1,2,4−6
are determined by XRD (CIF files CCDC nos. 2341480 (CuLL
1
), 2341468 (CuLL
2
), 2341478 (CuLL
4
), 2341477 (CuLL
5
), and 2341479 (CuLL
6
)). The biological activity of the complexes is studied. The adducts with L
1
, L
2
, and L
6
exhibit a significantly higher anti-protist activity than chloroquine used as the reference compound.</description><subject>Adducts</subject><subject>Aminobenzimidazole</subject><subject>Benzaldehyde</subject><subject>Biological activity</subject><subject>Biological properties</subject><subject>Chemical analysis</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copper</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Magnetochemistry</subject><subject>Molecular structure</subject><subject>NMR spectroscopy</subject><subject>Physical Chemistry</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kM1Lw0AQxYMoWKt_gLeAlxaMzu7mY-OtDX4Uigqt57DZTNqUNBt3EzE9-Le7pYIH8TS_Yd57A89xLgncEML82wWBCBjlPvVDAJ_xI2dAQuAeY4QfW7Znb38_dc6M2QAQgCAeOF-JahrUo9ls7FJv9OwtlekrsS1rNc6w3okqx3Wfozu1i-ory1rsVI1uorZNhZ9o7txFX7drNKW5dhet7mTbabT8qpWNbss9izp3p6Wq1KqUonInsi0_yrY_d04KURm8-JlD5-3hfpk8efOXx1kymXuSxLz1EKIoo0BkhrLgHItYQgGMA5MEkBc5lUGGgQAS54GkcRggjZiMIt-XkheUDZ2rQ26j1XuHpk03qtO1fZkyQkPbHGOxVZGDSmpljMYibXS5FbpPCaT7mtM_NVsPPXiM1dYr1L_J_5u-AdW4gAk</recordid><startdate>20240801</startdate><enddate>20240801</enddate><creator>Chal’tsev, B. V.</creator><creator>Burlov, A. S.</creator><creator>Vlasenko, V. G.</creator><creator>Koshchienko, Yu. V.</creator><creator>Zubenko, A. A.</creator><creator>Klimenko, A. I.</creator><creator>Lazarenko, V. A.</creator><creator>Mashchenko, S. A.</creator><creator>Korshunova, E. V.</creator><creator>Lifintseva, T. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240801</creationdate><title>Copper(II) 2-(N-Tosylamino)benzaldehyde Benzoylhydrazone Complexes: Synthesis, Structures, Properties, and Biological Activity</title><author>Chal’tsev, B. V. ; Burlov, A. S. ; Vlasenko, V. G. ; Koshchienko, Yu. V. ; Zubenko, A. A. ; Klimenko, A. I. ; Lazarenko, V. A. ; Mashchenko, S. A. ; Korshunova, E. V. ; Lifintseva, T. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c198t-e077b201cbecf88ef9c0f03803c10e8fd2c5be5a019d5c2965e273c7744cc8f23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Adducts</topic><topic>Aminobenzimidazole</topic><topic>Benzaldehyde</topic><topic>Biological activity</topic><topic>Biological properties</topic><topic>Chemical analysis</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copper</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Magnetochemistry</topic><topic>Molecular structure</topic><topic>NMR spectroscopy</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chal’tsev, B. V.</creatorcontrib><creatorcontrib>Burlov, A. S.</creatorcontrib><creatorcontrib>Vlasenko, V. G.</creatorcontrib><creatorcontrib>Koshchienko, Yu. V.</creatorcontrib><creatorcontrib>Zubenko, A. A.</creatorcontrib><creatorcontrib>Klimenko, A. I.</creatorcontrib><creatorcontrib>Lazarenko, V. A.</creatorcontrib><creatorcontrib>Mashchenko, S. A.</creatorcontrib><creatorcontrib>Korshunova, E. V.</creatorcontrib><creatorcontrib>Lifintseva, T. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chal’tsev, B. V.</au><au>Burlov, A. S.</au><au>Vlasenko, V. G.</au><au>Koshchienko, Yu. V.</au><au>Zubenko, A. A.</au><au>Klimenko, A. I.</au><au>Lazarenko, V. A.</au><au>Mashchenko, S. A.</au><au>Korshunova, E. V.</au><au>Lifintseva, T. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copper(II) 2-(N-Tosylamino)benzaldehyde Benzoylhydrazone Complexes: Synthesis, Structures, Properties, and Biological Activity</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2024-08-01</date><risdate>2024</risdate><volume>50</volume><issue>8</issue><spage>543</spage><epage>556</epage><pages>543-556</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>A number of new copper(II) complexes of 2-(
N
-tosylamino)benzaldehyde benzoylhydrazone (H
2
L) CuLL
n
(
n
= 1–6) with heterocyclic donor ligands (L
1
= 1-propyl-2-aminobenzimidazole, L
2
= 1‑hexyl-2-aminobenzimidazole, L
3
= 1-octyl-2-aminobenzimidazole, L
4
= 2,2'-bipyridine, L
5
= 1,10-phenanthroline, and L
6
= 2-aminopyridine) is synthesized. The structures and compositions of the synthesized compounds are determined by elemental analysis,
1
Н NMR spectroscopy, IR spectroscopy, and magnetochemistry. The molecular structures of complexes CuLL
1,2,4−6
are determined by XRD (CIF files CCDC nos. 2341480 (CuLL
1
), 2341468 (CuLL
2
), 2341478 (CuLL
4
), 2341477 (CuLL
5
), and 2341479 (CuLL
6
)). The biological activity of the complexes is studied. The adducts with L
1
, L
2
, and L
6
exhibit a significantly higher anti-protist activity than chloroquine used as the reference compound.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328424600438</doi><tpages>14</tpages></addata></record> |
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| subjects | Adducts Aminobenzimidazole Benzaldehyde Biological activity Biological properties Chemical analysis Chemical synthesis Chemistry Chemistry and Materials Science Copper Infrared spectroscopy Inorganic Chemistry Magnetochemistry Molecular structure NMR spectroscopy Physical Chemistry |
| title | Copper(II) 2-(N-Tosylamino)benzaldehyde Benzoylhydrazone Complexes: Synthesis, Structures, Properties, and Biological Activity |
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