Synthesis of 3-Substituted 1-(Dichloromethyl)adamantanes

Synthesis of 3-Substituted 1-(Dichloromethyl)adamantanes

Transformations of 1-(dichloromethyl)adamantane and its derivatives in strongly acidic media have been studied. The nitroxylation of the title compound has been found not to be accompanied by nitrolysis of the dichloromethyl group. A series of 3-substituted 1-(dichloromethyl)adamantanes have been ob...

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Veröffentlicht in:Russian journal of organic chemistry 2024-09, Vol.60 (9), p.1647-1653
Hauptverfasser: Shiryaev, V. A., Eremeev, D. O., Klimochkin, Yu. N.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Nitrolysis
Organic Chemistry
Substitutes
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Zusammenfassung:Transformations of 1-(dichloromethyl)adamantane and its derivatives in strongly acidic media have been studied. The nitroxylation of the title compound has been found not to be accompanied by nitrolysis of the dichloromethyl group. A series of 3-substituted 1-(dichloromethyl)adamantanes have been obtained via genera­tion of tertiary carbenium ion; the conservation of the dichloromethyl group in the products makes them promising for further modification.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428024090045