Radium separation from thorium and manufacturing of targets by precipitation method

We have proposed to produce a 229 Th/ 225 Ac generator by neutron irradiation of the 228 Ra target, which is a decay product from 232 Th. The solutions containing 232 Th and 228 Ra were obtained through the thermal chemical conversion method to dissolve the ThO 2 . Then, the separation of 228 Ra fro...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2024, Vol.333 (11), p.6039-6046
Hauptverfasser: Yin, Feng, Fukutani, Satoshi, Toyama, Mari, Yamamura, Tomoo, Suzuki, Tatsuya
Format: Artikel
Sprache:eng
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Zusammenfassung:We have proposed to produce a 229 Th/ 225 Ac generator by neutron irradiation of the 228 Ra target, which is a decay product from 232 Th. The solutions containing 232 Th and 228 Ra were obtained through the thermal chemical conversion method to dissolve the ThO 2 . Then, the separation of 228 Ra from thorium solutions through co-precipitation with magnesium was studied. It was confirmed that radium is coprecipitated by this method. It was also confirmed that the precipitated magnesium carbonate can be easily converted to magnesium oxide. The decontamination of thorium from precipitated radium was investigated, and it was found that a rough decontamination of thorium was achieved by co-precipitation methods. The decontamination of thorium depends on the chemical conversion conditions and the dissolution methods used.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-024-09496-5