Amorphous Nanomaterials: Emerging Catalysts for Electrochemical Carbon Dioxide Reduction

In the past decades, the rapid depletion of non‐renewable energy sources has caused growing energy crisis and increasing emissions of carbon dioxide (CO2), which aggravates global warming and catastrophic climate change. Electrocatalysis is regarded as an effective method for consuming atmospheric CO2 and simultaneously alleviating the energy problem by converting CO2 into high value‐added chemicals. Amorphous nanomaterials with long‐range disordered structures possess abundant highly unsaturated atomic sites and dangling bonds on their surfaces, thus providing a large number of active sites, and show unique electronic structures compared to their crystalline counterparts due to the distinct atomic arrangements. Therefore, amorphous nanomaterials are recently demonstrated as highly efficient catalysts for diverse electrocatalytic reactions, including electrocatalytic CO2 reduction reaction (CO2RR). Here the rational synthesis and electrocatalytic performance of newly emerging amorphous nanomaterials will be outlined for electrocatalytic CO2RR. Importantly, the intrinsic merits of these amorphous catalysts in CO2RR processes will be summarized and highlighted. Finally, these perspectives on the remaining challenges and some potential future directions in this emerging field will also be provided. Amorphous nanomaterials with long‐range disordered structures are recently demonstrated as emerging catalysts for electrocatalytic carbon dioxide (CO2) reduction reaction (CO2RR). This review outlines the rational synthesis and intrinsic merits of amorphous electrocatalysts for highly efficient CO2RR. Perspectives on the remaining challenges and some potential future directions in this exciting field have also been provided.