Supported g-C3N4/WO3 mixed layers for photocatalytic water remediation
g-C 3 N 4 layers with good mechanical properties, including their cohesion and adhesion to stainless-steel supports, were prepared by the quantitative electrophoretic co-deposition of g-C 3 N 4 and WO 3 nanocrystals. It was carried out in a mixture of organic solvents by applying a voltage of 750 V....
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Veröffentlicht in: | Chemical papers 2024-11, Vol.78 (16), p.8749-8757 |
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Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | g-C
3
N
4
layers with good mechanical properties, including their cohesion and adhesion to stainless-steel supports, were prepared by the quantitative electrophoretic co-deposition of g-C
3
N
4
and WO
3
nanocrystals. It was carried out in a mixture of organic solvents by applying a voltage of 750 V. The typical layer area density was 0.64 mg cm
–2
. The photocatalytic degradation of 4-chlorophenol under blue-light irradiation showed that the performance of stable composite layers containing 25–50 wt.% of WO
3
was only slightly weaker than that of unstable pristine g-C
3
N
4
ones. The high photocatalytic performance was due to g-C
3
N
4
, while WO
3
contributed to a good mechanical resistance of layers in stirred water. Finally, the composite layers exhibited a very high 4-chlorophenol mineralization of 75% in 24 h, even higher than the corresponding suspensions. Owing to their stability in water and performance, the developed layers are suitable for applications in environmental technologies.
Graphic Abstract |
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ISSN: | 0366-6352 2585-7290 1336-9075 |
DOI: | 10.1007/s11696-024-03706-w |