Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOF (Small 42/2024)

Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOF (Small 42/2024)

Intrusion Pressure The high vapor confined within the hydrophobic Cu2(tebpz) metal–organic framework led to a counterintuitive trend of the intrusion pressure with temperature, compared to naïve interpretations of the classical Young‐Laplace law. This is due to a peculiar combination of the geometri...

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Veröffentlicht in:Small (Weinheim an der Bergstrasse, Germany) Germany), 2024-10, Vol.20 (42), p.n/a
Hauptverfasser: Merchiori, Sebastiano, Donne, Andrea Le, Bhatia, Ribhu, Alvelli, Marta, Yu, Jiang‐Jing, Wu, Xu‐Dong, Li, Mian, Li, Dan, Scheller, Lukasz, Lowe, Alexander R., Geppert‐Rybczynska, Monika, Trump, Benjamin A., Yakovenko, Andrey A., Chorążewski, Mirosław, Zajdel, Paweł, Grosu, Yaroslav, Meloni, Simone
Format: Artikel
Sprache:eng
Schlagworte:
Hydrophobicity
Intrusion
intrusion pressure
Metal-organic frameworks
microporous materials
Porous materials
Porous media
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Zusammenfassung:Intrusion Pressure The high vapor confined within the hydrophobic Cu2(tebpz) metal–organic framework led to a counterintuitive trend of the intrusion pressure with temperature, compared to naïve interpretations of the classical Young‐Laplace law. This is due to a peculiar combination of the geometrical and chemical characteristics of the porous medium, favoring the formation of a dense vapor inside the material. More in article number 2402173, Andrea Le Donne, Pawel Zajdel, Yaroslav Grosu, and co‐workers.
ISSN:1613-6810
1613-6829
DOI:10.1002/smll.202470310