Efficient LED-driven MOF-catalysis for aerobic C–H and C–C bond oxidation
A novel LED-driven aerobic C–H oxidation is reported via MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic h...
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| Veröffentlicht in: | Catalysis science & technology 2024-10, Vol.14 (20), p.6041-6054 |
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| container_title | Catalysis science & technology |
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| creator | Sheykhan, Mehdi Bahmani, Mona Abbasnia, Masoumeh |
| description | A novel LED-driven aerobic C–H oxidation is reported via MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic hydrocarbons were also successfully oxidized under these conditions indicating a broad, extendable scope. |
| doi_str_mv | 10.1039/D4CY00892H |
| format | Article |
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This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. 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| fulltext | fulltext |
| identifier | ISSN: 2044-4753 |
| ispartof | Catalysis science & technology, 2024-10, Vol.14 (20), p.6041-6054 |
| issn | 2044-4753 2044-4761 |
| language | eng |
| recordid | cdi_proquest_journals_3116243661 |
| source | Royal Society Of Chemistry Journals |
| subjects | Alkynes Catalysis Covalent bonds Metal-organic frameworks Oxidation Oxidizing agents Oxygenation Polycyclic aromatic hydrocarbons Room temperature |
| title | Efficient LED-driven MOF-catalysis for aerobic C–H and C–C bond oxidation |
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