Efficient LED-driven MOF-catalysis for aerobic C–H and C–C bond oxidation

Efficient LED-driven MOF-catalysis for aerobic C–H and C–C bond oxidation

A novel LED-driven aerobic C–H oxidation is reported via MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic h...

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Veröffentlicht in:Catalysis science & technology 2024-10, Vol.14 (20), p.6041-6054
Hauptverfasser: Sheykhan, Mehdi, Bahmani, Mona, Abbasnia, Masoumeh
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Catalysis
Covalent bonds
Metal-organic frameworks
Oxidation
Oxidizing agents
Oxygenation
Polycyclic aromatic hydrocarbons
Room temperature
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Zusammenfassung:A novel LED-driven aerobic C–H oxidation is reported via MOF catalysis, eliminating the need for metal sources, additives, or oxidants. This approach also works well with aerobic oxygenation of C–H bonds and C–C cleavage/oxygenation of both alkenes and alkynes all at room temperature. Polyaromatic hydrocarbons were also successfully oxidized under these conditions indicating a broad, extendable scope.
ISSN:2044-4753
2044-4761
DOI:10.1039/D4CY00892H