Generation of hydrogen from various aqueous media using gamma radiation

Hydrogen generation was obtained with homogeneous n-C 6 H 14 , 88.5% n-C 6 H 14 +11.5% H 2 O, 50% n-C 6 H 14 +50% H 2 O and 11.5% n-C 6 H 14 +88.5% H 2 O and heterogeneous Al 2 O 3 +n-C 6 H 14 , Al 2 O 3 +88.5% n-C 6 H 14 +11.5% H 2 O, Al 2 O 3 +50% n-C 6 H 14 +50% H 2 O and Al 2 O 3 +11.5% n-C 6 H...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2024-10, Vol.333 (10), p.5161-5171
Hauptverfasser: Ali, Imran, Imanova, Gunel, Agayev, Teymur, Aliyev, Anar, Kurniawan, Tonni Agustiono, Jumah, Abdulrahman Bin
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Sprache:eng
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Zusammenfassung:Hydrogen generation was obtained with homogeneous n-C 6 H 14 , 88.5% n-C 6 H 14 +11.5% H 2 O, 50% n-C 6 H 14 +50% H 2 O and 11.5% n-C 6 H 14 +88.5% H 2 O and heterogeneous Al 2 O 3 +n-C 6 H 14 , Al 2 O 3 +88.5% n-C 6 H 14 +11.5% H 2 O, Al 2 O 3 +50% n-C 6 H 14 +50% H 2 O and Al 2 O 3 +11.5% n-C 6 H 14 +88.5% H 2 O systems. Hydrocarbons (methane, ethane, propane, butane, pentane, and hexane) and other organic molecules (methanol, acetaldehyde, and acetic acid) were also used for optimization. The activation energies were 3.50 and 3.74 kJ/mol for Al 2 O 3 +n-C 6 H 14 and Al 2 O 3 +C 6 H 14 +H 2 O systems. Maximum hydrogen produced was 54.0×1017 molecules/g.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-024-09670-9