Flexible, transparent, and durable slippery liquid‐infused porous surface achieved by void‐centered PVDF‐co‐HFP membrane for self‐cleaning antifog coating

Bioinspired smart surfaces, such as slippery liquid‐infused porous surfaces (SLIPS), have garnered significant attention due to their efficacy in self‐cleaning, antifouling, and antibacterial applications. Despite their advantages, SLIPS exhibit limitations such as compromised transparency, insufficient stability, and limited slippery performance, which have hindered their widespread practical use. To address these challenges, this article proposes a rational design utilizing a void‐centered poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF) membrane for slippery liquid‐infused porous surfaces with exceptional flexibility, transparency, durability, and superior slippery performance. These advancements promise to enhance high‐performance, self‐cleaning, and antifogging coatings. The membranes, featuring large‐area, thickness‐customizable void‐centered PVDF, are fabricated through a two‐step process involving phase separation and selective etching. The utilization of PVDF polymer, which has a refractive index similar to that of silicon‐based lubricant oil, enhances transparency, while macrovoids positioned at the membrane's center, acting as oil reservoirs, improve the stability and performance of the SLIPS surfaces. Experimental findings demonstrate remarkable transparency of up to 93% in the visible light range and a lubricant oil uptake of 2.32 at a porosity of 70%. Moreover, the developed SLIPS exhibit outstanding durability, maintaining slippery performance with sliding angles of