Exploring Ferrocenyl Imine‐Phosphane Complexes in Gold(I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant
Another class of gold(I) redox‐switchable catalysts, incorporating ferrocenyl phosphane‐imines, enriches the existing library of gold(I) complexes. Our catalyst proves efficacy in gold(I)‐catalyzed cyclizations of furans and benzamides, exhibiting reversible “on‐off” switching. Furthermore, we explo...
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Veröffentlicht in: | Advanced synthesis & catalysis 2024-09, Vol.366 (18), p.3845-3852 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Another class of gold(I) redox‐switchable catalysts, incorporating ferrocenyl phosphane‐imines, enriches the existing library of gold(I) complexes. Our catalyst proves efficacy in gold(I)‐catalyzed cyclizations of furans and benzamides, exhibiting reversible “on‐off” switching. Furthermore, we explored the unconventional role of “Magic Blue”, commonly used as an oxidizing agent in various organic transformations, as a potential activator of the Au−Cl bond, initiating conventional gold(I) catalysis. |
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ISSN: | 1615-4150 1615-4169 |
DOI: | 10.1002/adsc.202400593 |