Highly Stereoselective Synthesis of 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration/Sonogashira Coupling Sequence
Alkynylation of alkenyl bromoarenes via aryl to vinyl 1,4‐palladium migration/copper‐free Sonogashira coupling sequence has been developed. This approach provides a facile methodology for the highly stereoselective synthesis of multi‐substituted 1,3‐enynes in good to excellent yields and regioselect...
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| Veröffentlicht in: | ChemCatChem 2024-08, Vol.16 (16), p.n/a |
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| creator | Chen, Zheng‐Yu Ji, Xiao‐Ming Wang, Xue Asgari, Motahareh Fu, Jian‐Guo Zhang, Shu‐Sheng Feng, Chen‐Guo |
| description | Alkynylation of alkenyl bromoarenes via aryl to vinyl 1,4‐palladium migration/copper‐free Sonogashira coupling sequence has been developed. This approach provides a facile methodology for the highly stereoselective synthesis of multi‐substituted 1,3‐enynes in good to excellent yields and regioselectivities.
Sonogashira Coupling after 1,4‐Palladium Migration: An aryl to vinyl 1,4‐palladium migration/ Sonogashira Coupling sequence has been achieved for the highly stereoselective synthesis of multi‐substituted 1,3‐enynes. |
| doi_str_mv | 10.1002/cctc.202400478 |
| format | Article |
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Sonogashira Coupling after 1,4‐Palladium Migration: An aryl to vinyl 1,4‐palladium migration/ Sonogashira Coupling sequence has been achieved for the highly stereoselective synthesis of multi‐substituted 1,3‐enynes.</description><subject>Aromatic compounds</subject><subject>Coupling</subject><subject>C−H Functionalization</subject><subject>Enyne</subject><subject>Palladium</subject><subject>Palladium Migration</subject><subject>Sonogashira Reaction</subject><subject>Stereoselectivity</subject><subject>Synthesis</subject><issn>1867-3880</issn><issn>1867-3899</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNqFkEFLwzAUx4soOKdXzwGv6_aSpkt6HGU6YaLQ4bVkWdpldMlM2kk9-RH8jH4SOybz6On94f1-78E_CG4xDDEAGUlZyyEBQgEo42dBD_MxCyOeJOenzOEyuPJ-AzBOIhb3go-ZLtdVi7JaOWW9qpSs9V6hrDX1WnntkS0QHkTfn19T0xrl0V4LNHFthWqLXrXpAh7Qbv0iqkqsdLNFT7p0otbWjDJrbCn8WjuBUtvsKm1KlKm3RhmproOLQlRe3fzOfrC4ny7SWTh_fnhMJ_NQEkZ4iNWS05gAx5JGQjBCWAKcxRSDXFKMV3HCaCELRYkUHJiiFCJ2oGHMCY_6wd3x7M7Z7rGv841tnOk-5hF0KgYc0Y4aHinprPdOFfnO6a1wbY4hP9SbH-rNT_V2QnIU3nWl2n_oPE0X6Z_7A-E_f9I</recordid><startdate>20240826</startdate><enddate>20240826</enddate><creator>Chen, Zheng‐Yu</creator><creator>Ji, Xiao‐Ming</creator><creator>Wang, Xue</creator><creator>Asgari, Motahareh</creator><creator>Fu, Jian‐Guo</creator><creator>Zhang, Shu‐Sheng</creator><creator>Feng, Chen‐Guo</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-9899-9489</orcidid></search><sort><creationdate>20240826</creationdate><title>Highly Stereoselective Synthesis of 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration/Sonogashira Coupling Sequence</title><author>Chen, Zheng‐Yu ; Ji, Xiao‐Ming ; Wang, Xue ; Asgari, Motahareh ; Fu, Jian‐Guo ; Zhang, Shu‐Sheng ; Feng, Chen‐Guo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2728-1eb8452081c43aa722790875410cb411d5974fcfe42ca807e4403781c4068283</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Aromatic compounds</topic><topic>Coupling</topic><topic>C−H Functionalization</topic><topic>Enyne</topic><topic>Palladium</topic><topic>Palladium Migration</topic><topic>Sonogashira Reaction</topic><topic>Stereoselectivity</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Zheng‐Yu</creatorcontrib><creatorcontrib>Ji, Xiao‐Ming</creatorcontrib><creatorcontrib>Wang, Xue</creatorcontrib><creatorcontrib>Asgari, Motahareh</creatorcontrib><creatorcontrib>Fu, Jian‐Guo</creatorcontrib><creatorcontrib>Zhang, Shu‐Sheng</creatorcontrib><creatorcontrib>Feng, Chen‐Guo</creatorcontrib><collection>CrossRef</collection><jtitle>ChemCatChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Zheng‐Yu</au><au>Ji, Xiao‐Ming</au><au>Wang, Xue</au><au>Asgari, Motahareh</au><au>Fu, Jian‐Guo</au><au>Zhang, Shu‐Sheng</au><au>Feng, Chen‐Guo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Stereoselective Synthesis of 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration/Sonogashira Coupling Sequence</atitle><jtitle>ChemCatChem</jtitle><date>2024-08-26</date><risdate>2024</risdate><volume>16</volume><issue>16</issue><epage>n/a</epage><issn>1867-3880</issn><eissn>1867-3899</eissn><abstract>Alkynylation of alkenyl bromoarenes via aryl to vinyl 1,4‐palladium migration/copper‐free Sonogashira coupling sequence has been developed. This approach provides a facile methodology for the highly stereoselective synthesis of multi‐substituted 1,3‐enynes in good to excellent yields and regioselectivities.
Sonogashira Coupling after 1,4‐Palladium Migration: An aryl to vinyl 1,4‐palladium migration/ Sonogashira Coupling sequence has been achieved for the highly stereoselective synthesis of multi‐substituted 1,3‐enynes.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cctc.202400478</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-9899-9489</orcidid></addata></record> |
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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aromatic compounds Coupling C−H Functionalization Enyne Palladium Palladium Migration Sonogashira Reaction Stereoselectivity Synthesis |
| title | Highly Stereoselective Synthesis of 1,3‐Enynes via Aryl to Vinyl 1,4‐Palladium Migration/Sonogashira Coupling Sequence |
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