2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4'-bipyridine: Synthesis and Structure
Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et 2 mal 2– ) and 4,4'-bipyridine (4,4'-bipy) are synthesized: {[Zn(H 2 O)(4,4'-bipy)(Et 2 mal)]·0.5C 2 H 5 OH·1.5H 2 O} n ( I ) and {[Zn 4 (H 2 O) 2 (4,4'-bipy) 3 (Et 2 mal) 4 ]·6H 2 O} n ( II ). Accordi...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2024, Vol.50 (7), p.469-475 |
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| container_title | Russian journal of coordination chemistry |
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| creator | Chistyakov, A. S. Zorina-Tikhonova, E. N. Vologzhanina, A. V. Kiskin, M. A. Eremenko, I. L. |
| description | Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et
2
mal
2–
) and 4,4'-bipyridine (4,4'-bipy) are synthesized: {[Zn(H
2
O)(4,4'-bipy)(Et
2
mal)]·0.5C
2
H
5
OH·1.5H
2
O}
n
(
I
) and {[Zn
4
(H
2
O)
2
(4,4'-bipy)
3
(Et
2
mal)
4
]·6H
2
O}
n
(
II
). According to the XRD data (CIF files CCDC nos. 2323336 (
I
) and 2323337 (
II
)), both compounds are 2D polymers with the
sql
and
bey
topology, respectively. The choice of the initial zinc salt and solvent predetermines the compositions and structures of the polymers under similar synthesis conditions. |
| doi_str_mv | 10.1134/S1070328424600128 |
| format | Article |
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2
mal
2–
) and 4,4'-bipyridine (4,4'-bipy) are synthesized: {[Zn(H
2
O)(4,4'-bipy)(Et
2
mal)]·0.5C
2
H
5
OH·1.5H
2
O}
n
(
I
) and {[Zn
4
(H
2
O)
2
(4,4'-bipy)
3
(Et
2
mal)
4
]·6H
2
O}
n
(
II
). According to the XRD data (CIF files CCDC nos. 2323336 (
I
) and 2323337 (
II
)), both compounds are 2D polymers with the
sql
and
bey
topology, respectively. The choice of the initial zinc salt and solvent predetermines the compositions and structures of the polymers under similar synthesis conditions.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328424600128</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Anions ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coordination compounds ; Coordination polymers ; Inorganic Chemistry ; Physical Chemistry ; Topology ; Zinc compounds ; Zinc coordination ; Zinc salts</subject><ispartof>Russian journal of coordination chemistry, 2024, Vol.50 (7), p.469-475</ispartof><rights>Pleiades Publishing, Ltd. 2024. ISSN 1070-3284, Russian Journal of Coordination Chemistry, 2024, Vol. 50, No. 7, pp. 469–475. © Pleiades Publishing, Ltd., 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070328424600128$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070328424600128$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Chistyakov, A. S.</creatorcontrib><creatorcontrib>Zorina-Tikhonova, E. N.</creatorcontrib><creatorcontrib>Vologzhanina, A. V.</creatorcontrib><creatorcontrib>Kiskin, M. A.</creatorcontrib><creatorcontrib>Eremenko, I. L.</creatorcontrib><title>2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4'-bipyridine: Synthesis and Structure</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et
2
mal
2–
) and 4,4'-bipyridine (4,4'-bipy) are synthesized: {[Zn(H
2
O)(4,4'-bipy)(Et
2
mal)]·0.5C
2
H
5
OH·1.5H
2
O}
n
(
I
) and {[Zn
4
(H
2
O)
2
(4,4'-bipy)
3
(Et
2
mal)
4
]·6H
2
O}
n
(
II
). According to the XRD data (CIF files CCDC nos. 2323336 (
I
) and 2323337 (
II
)), both compounds are 2D polymers with the
sql
and
bey
topology, respectively. The choice of the initial zinc salt and solvent predetermines the compositions and structures of the polymers under similar synthesis conditions.</description><subject>Anions</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Coordination polymers</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><subject>Topology</subject><subject>Zinc compounds</subject><subject>Zinc coordination</subject><subject>Zinc salts</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNplkE1LAzEQhoMoWKs_wFvAgwqu5nt3vZXWj0JBoT15WbLZrE3ZJjXJIvvvTangQYZhhnmfeQcGgEuM7jGm7GGJUY4oKRhhAiFMiiMwwgIVGaW4OE59krO9fgrOQtgkBCFejsAXmcGpc74xVkbjLHx33bDVPkDXwg97M5_fwm8T13BmdFwP3VZ2zhoFJ8o0aSZt2glQ2gayO3ad1WY3eJPM9CNcDjaudTAHeRl9r2Lv9Tk4aWUX9MVvHYPV89Nq-pot3l7m08ki22EuYiaIQlzRRiMlCyVzVCJec1LmmBU0pVINE6JVRMs6V22tWS6IpCSFaomgY3B1sN1599XrEKuN671NFyuKSs7LnAmeKHKgws4b-6n9H4VRtf9s9e-z9AegfGqH</recordid><startdate>2024</startdate><enddate>2024</enddate><creator>Chistyakov, A. S.</creator><creator>Zorina-Tikhonova, E. N.</creator><creator>Vologzhanina, A. V.</creator><creator>Kiskin, M. A.</creator><creator>Eremenko, I. L.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope/></search><sort><creationdate>2024</creationdate><title>2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4'-bipyridine: Synthesis and Structure</title><author>Chistyakov, A. S. ; Zorina-Tikhonova, E. N. ; Vologzhanina, A. V. ; Kiskin, M. A. ; Eremenko, I. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p156t-62c05c3de0ca8ca70905b52971483148ccd466fc2eab7cfbe4762a32323cf263</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Anions</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination compounds</topic><topic>Coordination polymers</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Topology</topic><topic>Zinc compounds</topic><topic>Zinc coordination</topic><topic>Zinc salts</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chistyakov, A. S.</creatorcontrib><creatorcontrib>Zorina-Tikhonova, E. N.</creatorcontrib><creatorcontrib>Vologzhanina, A. V.</creatorcontrib><creatorcontrib>Kiskin, M. A.</creatorcontrib><creatorcontrib>Eremenko, I. L.</creatorcontrib><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chistyakov, A. S.</au><au>Zorina-Tikhonova, E. N.</au><au>Vologzhanina, A. V.</au><au>Kiskin, M. A.</au><au>Eremenko, I. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4'-bipyridine: Synthesis and Structure</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2024</date><risdate>2024</risdate><volume>50</volume><issue>7</issue><spage>469</spage><epage>475</epage><pages>469-475</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et
2
mal
2–
) and 4,4'-bipyridine (4,4'-bipy) are synthesized: {[Zn(H
2
O)(4,4'-bipy)(Et
2
mal)]·0.5C
2
H
5
OH·1.5H
2
O}
n
(
I
) and {[Zn
4
(H
2
O)
2
(4,4'-bipy)
3
(Et
2
mal)
4
]·6H
2
O}
n
(
II
). According to the XRD data (CIF files CCDC nos. 2323336 (
I
) and 2323337 (
II
)), both compounds are 2D polymers with the
sql
and
bey
topology, respectively. The choice of the initial zinc salt and solvent predetermines the compositions and structures of the polymers under similar synthesis conditions.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328424600128</doi><tpages>7</tpages></addata></record> |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Anions Chemical synthesis Chemistry Chemistry and Materials Science Coordination compounds Coordination polymers Inorganic Chemistry Physical Chemistry Topology Zinc compounds Zinc coordination Zinc salts |
| title | 2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4'-bipyridine: Synthesis and Structure |
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