2D Coordination Polymers of Zn(II) with Diethylmalonic Acid Dianions and 4,4'-bipyridine: Synthesis and Structure
Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et 2 mal 2– ) and 4,4'-bipyridine (4,4'-bipy) are synthesized: {[Zn(H 2 O)(4,4'-bipy)(Et 2 mal)]·0.5C 2 H 5 OH·1.5H 2 O} n ( I ) and {[Zn 4 (H 2 O) 2 (4,4'-bipy) 3 (Et 2 mal) 4 ]·6H 2 O} n ( II ). Accordi...
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| Veröffentlicht in: | Russian journal of coordination chemistry 2024, Vol.50 (7), p.469-475 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Two new coordination compounds of zinc(II) with diethylmalonic acid anions (Et
2
mal
2–
) and 4,4'-bipyridine (4,4'-bipy) are synthesized: {[Zn(H
2
O)(4,4'-bipy)(Et
2
mal)]·0.5C
2
H
5
OH·1.5H
2
O}
n
(
I
) and {[Zn
4
(H
2
O)
2
(4,4'-bipy)
3
(Et
2
mal)
4
]·6H
2
O}
n
(
II
). According to the XRD data (CIF files CCDC nos. 2323336 (
I
) and 2323337 (
II
)), both compounds are 2D polymers with the
sql
and
bey
topology, respectively. The choice of the initial zinc salt and solvent predetermines the compositions and structures of the polymers under similar synthesis conditions. |
|---|---|
| ISSN: | 1070-3284 1608-3318 |
| DOI: | 10.1134/S1070328424600128 |