Magnetic clusters as efficient EY-like spin-scattering centres in graphene

The spin scattering induced by magnetic adsorbates on graphene was studied using a combination of transport measurements on a graphene field effect transistor decorated with atomically precise nickel clusters and first principles calculations. A comparative study before and after deposition of Ni 4 clusters unambiguously corroborated the contribution of the added scatterers. An investigation of the spin scattering parameters as a function of the applied voltage indicated a cluster-induced Elliot-Yafet like spin scattering mechanism. Density functional theory calculations were used in combination with a tight-binding model to quantify the strength of the spin-orbit coupling terms induced by the adsorbed clusters. Exploring the ability of atomically precise magnetic Ni 4 scatterers to augment graphene's spin activity.