Synthesis of Microdispersed Ni1–xRux Alloys for Obtaining Metal-Carbon Nanocomposites in the Mode of Carbon Erosion
Using the method of reductive thermolysis of two-component precursors, a series of microdispersed alloys Ni 1– x Ru x containing up to 10 at % ruthenium was obtained. The effect of ruthenium content in the alloy on its activity in the catalytic pyrolysis of a mixture of C 2 –C 4 hydrocarbons to prod...
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| Veröffentlicht in: | Russian journal of general chemistry 2024-06, Vol.94 (6), p.1322-1333 |
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| container_title | Russian journal of general chemistry |
| container_volume | 94 |
| creator | Shivtsov, D. M. Popov, A. A. Afonnikova, S. D. Bauman, Yu. I. Plyusnin, P. E. Mishakov, I. V. Shubin, Yu. V. |
| description | Using the method of reductive thermolysis of two-component precursors, a series of microdispersed alloys Ni
1–
x
Ru
x
containing up to 10 at % ruthenium was obtained. The effect of ruthenium content in the alloy on its activity in the catalytic pyrolysis of a mixture of C
2
–C
4
hydrocarbons to produce carbon nanofibers (CNF) was studied. Using the Ni
0.98
Ru
0.02
sample as an example, the early stage of carbon erosion, leading to the disintegration of the alloy and to the formation of active particles, was studied in detail. The obtained alloys were used for the synthesis of metal-carbon nanocomposites Ni
1–
x
Ru
x
@CNF, which are promising materials for solving applied problems. |
| doi_str_mv | 10.1134/S1070363224060100 |
| format | Article |
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1–
x
Ru
x
containing up to 10 at % ruthenium was obtained. The effect of ruthenium content in the alloy on its activity in the catalytic pyrolysis of a mixture of C
2
–C
4
hydrocarbons to produce carbon nanofibers (CNF) was studied. Using the Ni
0.98
Ru
0.02
sample as an example, the early stage of carbon erosion, leading to the disintegration of the alloy and to the formation of active particles, was studied in detail. The obtained alloys were used for the synthesis of metal-carbon nanocomposites Ni
1–
x
Ru
x
@CNF, which are promising materials for solving applied problems.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363224060100</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Carbon fibers ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Disintegration ; Nanocomposites ; Nickel ; Pyrolysis ; Ruthenium ; Synthesis</subject><ispartof>Russian journal of general chemistry, 2024-06, Vol.94 (6), p.1322-1333</ispartof><rights>Pleiades Publishing, Ltd. 2024</rights><rights>Pleiades Publishing, Ltd. 2024.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c268t-65cd44c95a0d50c87ac5009f9beeb574546438207a26701f8e96323b0e77df53</cites><orcidid>0000-0002-1738-128X ; 0000-0003-1835-1901 ; 0000-0002-1156-5854 ; 0000-0002-2295-2446 ; 0000-0003-4029-2338 ; 0000-0002-7494-6240 ; 0000-0003-0831-5114</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363224060100$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363224060100$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Shivtsov, D. M.</creatorcontrib><creatorcontrib>Popov, A. A.</creatorcontrib><creatorcontrib>Afonnikova, S. D.</creatorcontrib><creatorcontrib>Bauman, Yu. I.</creatorcontrib><creatorcontrib>Plyusnin, P. E.</creatorcontrib><creatorcontrib>Mishakov, I. V.</creatorcontrib><creatorcontrib>Shubin, Yu. V.</creatorcontrib><title>Synthesis of Microdispersed Ni1–xRux Alloys for Obtaining Metal-Carbon Nanocomposites in the Mode of Carbon Erosion</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>Using the method of reductive thermolysis of two-component precursors, a series of microdispersed alloys Ni
1–
x
Ru
x
containing up to 10 at % ruthenium was obtained. The effect of ruthenium content in the alloy on its activity in the catalytic pyrolysis of a mixture of C
2
–C
4
hydrocarbons to produce carbon nanofibers (CNF) was studied. Using the Ni
0.98
Ru
0.02
sample as an example, the early stage of carbon erosion, leading to the disintegration of the alloy and to the formation of active particles, was studied in detail. The obtained alloys were used for the synthesis of metal-carbon nanocomposites Ni
1–
x
Ru
x
@CNF, which are promising materials for solving applied problems.</description><subject>Carbon fibers</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Disintegration</subject><subject>Nanocomposites</subject><subject>Nickel</subject><subject>Pyrolysis</subject><subject>Ruthenium</subject><subject>Synthesis</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp1kE1OwzAQhS0EEqVwAHaWWAfGcWwny6oqP1J_JNp95CROcZXawU4kuuMO3JCT4KiVWCBWM9L73hu9QeiWwD0hNHlYExBAOY3jBDgQgDM0IhzSiFIG52EPcjTol-jK-x0MCI9HqF8fTPemvPbY1nihS2cr7VvlvKrwUpPvz6-P1_4DT5rGHjyurcOropPaaLPFC9XJJppKV1iDl9LY0u5b63WnPNYGh1y8sJUakk_QzAXZmmt0UcvGq5vTHKPN42wzfY7mq6eX6WQelTFPu4izskqSMmMSKgZlKmTJALI6K5QqmEhYwhOaxiBkzAWQOlVZaEgLUEJUNaNjdHeMbZ1975Xv8p3tnQkXcwoZTVMBmQgUOVKhu_dO1Xnr9F66Q04gH56b_3lu8MRHjw-s2Sr3m_y_6Qd8FXv0</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Shivtsov, D. M.</creator><creator>Popov, A. A.</creator><creator>Afonnikova, S. D.</creator><creator>Bauman, Yu. I.</creator><creator>Plyusnin, P. E.</creator><creator>Mishakov, I. V.</creator><creator>Shubin, Yu. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1738-128X</orcidid><orcidid>https://orcid.org/0000-0003-1835-1901</orcidid><orcidid>https://orcid.org/0000-0002-1156-5854</orcidid><orcidid>https://orcid.org/0000-0002-2295-2446</orcidid><orcidid>https://orcid.org/0000-0003-4029-2338</orcidid><orcidid>https://orcid.org/0000-0002-7494-6240</orcidid><orcidid>https://orcid.org/0000-0003-0831-5114</orcidid></search><sort><creationdate>20240601</creationdate><title>Synthesis of Microdispersed Ni1–xRux Alloys for Obtaining Metal-Carbon Nanocomposites in the Mode of Carbon Erosion</title><author>Shivtsov, D. M. ; Popov, A. A. ; Afonnikova, S. D. ; Bauman, Yu. I. ; Plyusnin, P. E. ; Mishakov, I. V. ; Shubin, Yu. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c268t-65cd44c95a0d50c87ac5009f9beeb574546438207a26701f8e96323b0e77df53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Carbon fibers</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Disintegration</topic><topic>Nanocomposites</topic><topic>Nickel</topic><topic>Pyrolysis</topic><topic>Ruthenium</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shivtsov, D. M.</creatorcontrib><creatorcontrib>Popov, A. A.</creatorcontrib><creatorcontrib>Afonnikova, S. D.</creatorcontrib><creatorcontrib>Bauman, Yu. I.</creatorcontrib><creatorcontrib>Plyusnin, P. E.</creatorcontrib><creatorcontrib>Mishakov, I. V.</creatorcontrib><creatorcontrib>Shubin, Yu. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shivtsov, D. M.</au><au>Popov, A. A.</au><au>Afonnikova, S. D.</au><au>Bauman, Yu. I.</au><au>Plyusnin, P. E.</au><au>Mishakov, I. V.</au><au>Shubin, Yu. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Microdispersed Ni1–xRux Alloys for Obtaining Metal-Carbon Nanocomposites in the Mode of Carbon Erosion</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>94</volume><issue>6</issue><spage>1322</spage><epage>1333</epage><pages>1322-1333</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>Using the method of reductive thermolysis of two-component precursors, a series of microdispersed alloys Ni
1–
x
Ru
x
containing up to 10 at % ruthenium was obtained. The effect of ruthenium content in the alloy on its activity in the catalytic pyrolysis of a mixture of C
2
–C
4
hydrocarbons to produce carbon nanofibers (CNF) was studied. Using the Ni
0.98
Ru
0.02
sample as an example, the early stage of carbon erosion, leading to the disintegration of the alloy and to the formation of active particles, was studied in detail. The obtained alloys were used for the synthesis of metal-carbon nanocomposites Ni
1–
x
Ru
x
@CNF, which are promising materials for solving applied problems.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363224060100</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-1738-128X</orcidid><orcidid>https://orcid.org/0000-0003-1835-1901</orcidid><orcidid>https://orcid.org/0000-0002-1156-5854</orcidid><orcidid>https://orcid.org/0000-0002-2295-2446</orcidid><orcidid>https://orcid.org/0000-0003-4029-2338</orcidid><orcidid>https://orcid.org/0000-0002-7494-6240</orcidid><orcidid>https://orcid.org/0000-0003-0831-5114</orcidid></addata></record> |
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| ispartof | Russian journal of general chemistry, 2024-06, Vol.94 (6), p.1322-1333 |
| issn | 1070-3632 1608-3350 |
| language | eng |
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| source | SpringerLink Journals |
| subjects | Carbon fibers Chemistry Chemistry and Materials Science Chemistry/Food Science Disintegration Nanocomposites Nickel Pyrolysis Ruthenium Synthesis |
| title | Synthesis of Microdispersed Ni1–xRux Alloys for Obtaining Metal-Carbon Nanocomposites in the Mode of Carbon Erosion |
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