Synthesis of Microdispersed Ni1–xRux Alloys for Obtaining Metal-Carbon Nanocomposites in the Mode of Carbon Erosion

Using the method of reductive thermolysis of two-component precursors, a series of microdispersed alloys Ni 1– x Ru x containing up to 10 at % ruthenium was obtained. The effect of ruthenium content in the alloy on its activity in the catalytic pyrolysis of a mixture of C 2 –C 4 hydrocarbons to produce carbon nanofibers (CNF) was studied. Using the Ni 0.98 Ru 0.02 sample as an example, the early stage of carbon erosion, leading to the disintegration of the alloy and to the formation of active particles, was studied in detail. The obtained alloys were used for the synthesis of metal-carbon nanocomposites Ni 1– x Ru x @CNF, which are promising materials for solving applied problems.