Magmatic water content in HIMU basalts from the Cook-Austral Islands: constraints on degassing processes and source composition from clinopyroxene phenocrysts

The amount of water recycled during subduction is unclear. Water/Ce estimates in HIMU (high- 238 U/ 204 Pb) basalts are variable, ranging from  250 in glasses and melt inclusions. Because clinopyroxene (cpx) is a common early liquidus phase and the cpx/melt partitioning of water is well constrained,...

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Veröffentlicht in:Contributions to mineralogy and petrology 2024-09, Vol.179 (9), p.83, Article 83
Hauptverfasser: Bruce-Etzel, Leslie A., Marshall, Edward W., Lassiter, John C.
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Sprache:eng
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Zusammenfassung:The amount of water recycled during subduction is unclear. Water/Ce estimates in HIMU (high- 238 U/ 204 Pb) basalts are variable, ranging from  250 in glasses and melt inclusions. Because clinopyroxene (cpx) is a common early liquidus phase and the cpx/melt partitioning of water is well constrained, cpx phenocrysts provide an additional constraint on magmatic water contents. We present water and trace element concentrations in HIMU-basalt-hosted cpx phenocrysts from the Austral Islands. Calculated melt [H 2 O] (up to 4.3 wt.%) and H 2 O/Ce ratios (22–825) are higher than in olivine-hosted inclusions, as are estimated equilibration pressures. Correlation between estimated melt [H 2 O] and crystallization or entrapment pressure suggests significant water loss during magma ascent. Most ocean island basalts (OIBs) span a limited range in H 2 O (~ 1–1.5 wt.%), and low (
ISSN:0010-7999
1432-0967
DOI:10.1007/s00410-024-02160-x