Case Study of PVC Cables Exposed in Accelerated Thermal and Radiation Environment

The objective of the present research is to investigate the degradation phenomenon of Polyvinyl Chloride (PVC) cable jacket exposed under accelerated thermally aged at 100°C for 4 days then irradiated under n’s flux of 1.5x 1011 n’s / cm2.sec for 1 hr in PARR-2 reactor at PINSTECH. Thermal, mechanical and chemical etc. properties of degraded cable jacket were studied with respect to fresh sample. It was examined that plasticizer content in PVC matrix started to deplete under the effect of temperature which made the matrix more rigid. In addition, the interaction of radiation with polymeric chains weakens the hydrocarbon bonding. The hydrogen and chlorine ions ejected from PVC molecular chains recombine to form hydrogen chloride (HCl) which induces porosity by creating localized pitting. This phenomenon is known as dehydrochlorination which created scissioning in PVC materials. Hence, due to the synergistic effects of temperature and radiation aging, cracks were observed on the outer surface of cable jacket in 2 years equivalent time. This study concludes that cables having PVC insulation are not suitable for long term exposure (i.e. decades) in thermo-irradiation environment.