Investigation on concentration-dependent luminescence properties of high color purity red-emitting Pr3+ ion-doped sodium barium borate phosphors

The photoluminescence studies were carried out for Pr 3+ ion-doped NaBaB 9 o 15 phosphors by varying Pr 3+ ion concentrations. The formation of single-phase was confirmed through X-Ray diffraction analysis. FTIR analysis was made to identify functional groups presented in the studied phosphors. The...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2024-07, Vol.35 (20), p.1410, Article 1410
Hauptverfasser: Vanchinathan, S., Gnanavel, B., Vijayakumar, R.
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Sprache:eng
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Zusammenfassung:The photoluminescence studies were carried out for Pr 3+ ion-doped NaBaB 9 o 15 phosphors by varying Pr 3+ ion concentrations. The formation of single-phase was confirmed through X-Ray diffraction analysis. FTIR analysis was made to identify functional groups presented in the studied phosphors. The morphology of synthesized phosphors was examined through SEM analysis. As-prepared NaBaB 9 O 15 :xPr 3+ phosphors exhibit strong red emission peak with FWHM of 14 nm under blue excitation. In the studied phosphors, optimum dopant (Pr 3+ ions) concentration was found as 4 mol%. The CIE method was employed to find dominant giving out color of prepared phosphors. The color coordinates are passed through red region of CIE diagram and hence, the studied NBB:xPr 3+ phosphors have the ability to emit intense red color under blue excitation. Decay measurements are made to determine the fluorescent lifetime values of 1 D 2 excited level of Pr 3+ ions and the decay curves are well fitted to non-exponential curve fitting method. All the measurements were done as a function of Pr 3+ ion concentration at room temperature and the results were compared with similar literature results.
ISSN:0957-4522
1573-482X
DOI:10.1007/s10854-024-13160-9