Molecular engineering of metal-based photosensitizers with narrow band gap for efficient photodynamic therapy
Three iridium( iii ) complexes were designed with the purpose of elucidating the photo-physicochemical properties of iridium( iii ) complexes with narrow band gap at the electronic level. This study indicates that increasing the ligand rigidity and electron delocalization of the compounds can suppre...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2024-07, Vol.6 (58), p.753-756 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Shi, Pengmin Gong, Wenqi Zhao, Jian Jiao, Yubo Sun, Yanyan Fang, Lei Gou, Shaohua |
| description | Three iridium(
iii
) complexes were designed with the purpose of elucidating the photo-physicochemical properties of iridium(
iii
) complexes with narrow band gap at the electronic level. This study indicates that increasing the ligand rigidity and electron delocalization of the compounds can suppress the ring-stretching vibrations of the iridium(
iii
) complex, thus improving their photo-chemical activity and photocytotoxicity.
Three iridium(
iii
) complexes were designed with the purpose of investigating the photo-physicochemical behaviors of iridium(
iii
) complexes with narrow band gap for photodynamic therapy. |
| doi_str_mv | 10.1039/d4cc02347a |
| format | Article |
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iii
) complexes were designed with the purpose of elucidating the photo-physicochemical properties of iridium(
iii
) complexes with narrow band gap at the electronic level. This study indicates that increasing the ligand rigidity and electron delocalization of the compounds can suppress the ring-stretching vibrations of the iridium(
iii
) complex, thus improving their photo-chemical activity and photocytotoxicity.
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iii
) complexes were designed with the purpose of elucidating the photo-physicochemical properties of iridium(
iii
) complexes with narrow band gap at the electronic level. This study indicates that increasing the ligand rigidity and electron delocalization of the compounds can suppress the ring-stretching vibrations of the iridium(
iii
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iii
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iii
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iii
) complexes were designed with the purpose of elucidating the photo-physicochemical properties of iridium(
iii
) complexes with narrow band gap at the electronic level. This study indicates that increasing the ligand rigidity and electron delocalization of the compounds can suppress the ring-stretching vibrations of the iridium(
iii
) complex, thus improving their photo-chemical activity and photocytotoxicity.
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iii
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iii
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2024-07, Vol.6 (58), p.753-756 |
| issn | 1359-7345 1364-548X 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_3081103909 |
| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Chemical activity Energy gap Iridium compounds |
| title | Molecular engineering of metal-based photosensitizers with narrow band gap for efficient photodynamic therapy |
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