Carbon quantum dots/carbon-coated SnS2 as a high-performance potassium-ion battery cathode material

Potassium-ion batteries (PIBs) are considered to be an alternative to lithium-ion batteries because of their more affordable manufacturing cost and lower potential (2.936 V compared to standard hydrogen electrodes). However, the large ionic radius and unstable structure of potassium ions have hinder...

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Veröffentlicht in:Ionics 2024, Vol.30 (6), p.3265-3277
Hauptverfasser: Wu, Kaidan, Feng, Yefeng, Jiang, Wenqin, Zhang, Junming, Feng, Zuyong, He, Miao, Chen, Li, Wen, Kunhua, Xiong, Deping
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Sprache:eng
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Zusammenfassung:Potassium-ion batteries (PIBs) are considered to be an alternative to lithium-ion batteries because of their more affordable manufacturing cost and lower potential (2.936 V compared to standard hydrogen electrodes). However, the large ionic radius and unstable structure of potassium ions have hindered their satisfactory electrochemical performance from being satisfactory. In this study, a layered SnS 2 @CQDs composite material was prepared using hydrothermal and pyrolysis methods as a promising anode material for PIBs. The composite material possessed a significant specific surface area, and the layered structure of SnS 2 contributed to its unique potassium-ion intercalation/deintercalation properties. The anchoring of the CQDs and carbon coating restricted the volume effect of SnS 2 and enhanced the electron transfer efficiency. PIBs prepared from this electrode exhibited a high potassium storage capacity (235 mA h g −1 after 120 cycles at 100 mA g −1 ) and excellent cycling stability (144.8 mA h g −1 after 500 cycles at 500 mA g −1 ).
ISSN:0947-7047
1862-0760
DOI:10.1007/s11581-024-05539-9