Carbon quantum dots/carbon-coated SnS2 as a high-performance potassium-ion battery cathode material
Potassium-ion batteries (PIBs) are considered to be an alternative to lithium-ion batteries because of their more affordable manufacturing cost and lower potential (2.936 V compared to standard hydrogen electrodes). However, the large ionic radius and unstable structure of potassium ions have hinder...
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Veröffentlicht in: | Ionics 2024, Vol.30 (6), p.3265-3277 |
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Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Potassium-ion batteries (PIBs) are considered to be an alternative to lithium-ion batteries because of their more affordable manufacturing cost and lower potential (2.936 V compared to standard hydrogen electrodes). However, the large ionic radius and unstable structure of potassium ions have hindered their satisfactory electrochemical performance from being satisfactory. In this study, a layered SnS
2
@CQDs composite material was prepared using hydrothermal and pyrolysis methods as a promising anode material for PIBs. The composite material possessed a significant specific surface area, and the layered structure of SnS
2
contributed to its unique potassium-ion intercalation/deintercalation properties. The anchoring of the CQDs and carbon coating restricted the volume effect of SnS
2
and enhanced the electron transfer efficiency. PIBs prepared from this electrode exhibited a high potassium storage capacity (235 mA h g
−1
after 120 cycles at 100 mA g
−1
) and excellent cycling stability (144.8 mA h g
−1
after 500 cycles at 500 mA g
−1
). |
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ISSN: | 0947-7047 1862-0760 |
DOI: | 10.1007/s11581-024-05539-9 |