Thermodynamics of photoelectric devices

We study the nonequilibrium steady state thermodynamics of a photodevice which can operate as a solar cell or a photoconductor, depending on the degree of asymmetry of the junction. The thermodynamic efficiency is captured by a single coefficient of performance. Using a minimal model, we show that when the electron repulsion energy matches the transport gap of the junction, the photoconductor displays maximal response, performance and signal-to-noise ratio, while the same regime is always detrimental for the solar cell. Nevertheless, we find that electron repulsion is beneficial for the solar cell if it lies below the transport gap. Our work sheds important light on design principles for thermodynamically efficient photodevices in the presence of interactions.