Analysis of the intermediates of the catalytic system for the Chan—Evans—Lam reaction based on Cu(i) complex with N-heterocyclic carbene

Analysis of the intermediates of the catalytic system for the Chan—Evans—Lam reaction based on Cu(i) complex with N-heterocyclic carbene

The complex dynamic nature of the Chan—Evans—Lam catalytic system in the presence of CuCl complex with N-heterocyclic carbene (1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) was demonstrated. The appearance of metal nanoparticles in this system was theoretically and experimentally substantiated....

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Veröffentlicht in:Russian chemical bulletin 2024-05, Vol.73 (5), p.1182-1188
Hauptverfasser: Galushko, A. S., Skuratovich, V. A., Grudova, M. V., Ilyushenkova, V. V., Ivanova, N. M.
Format: Artikel
Sprache:eng
Schlagworte:
Carbenes
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Copper chloride
Full Articles
Inorganic Chemistry
Organic Chemistry
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Zusammenfassung:The complex dynamic nature of the Chan—Evans—Lam catalytic system in the presence of CuCl complex with N-heterocyclic carbene (1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) was demonstrated. The appearance of metal nanoparticles in this system was theoretically and experimentally substantiated.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-024-4233-7