Digital Light Processing of Soft Robotic Gripper with High Toughness and Self‐Healing Capability Achieved by Deep Eutectic Solvents

Inspired by nature's flexible and adaptable organisms, soft robotics are motorless robots made from highly compliant materials to work in confined environments and manipulate delicate objects. However, soft robots often suffer from early failure because of unexpected damage. At the same time, it is challenging to manufacture the geometrically complex structures of soft robots. This study introduces resins based on deep eutectic solvents (DES) to fabricate a pneumatically driven soft gripper using digital light processing (DLP). The resins consist of choline chloride (ChCl) as a hydrogen bond acceptor, glycerol (Gly), and acrylamide (AAm) as hydrogen bond donors. By utilizing the intense hydrogen bonding within DES, the resin can be rapidly cured by photopolymerization to form tough ionogels without chemical crosslinkers. The DES ionogels exhibit remarkable toughness and self‐healing performance compared to common hydrogels. Furthermore, the ionogels show not only efficient energy‐dissipating behavior but also achieve rapid self‐recovery. Finally, the DLP‐printed soft gripper from the DES‐based resin performs successful actuation and healing of macroscopic damages. This work presents a simple strategy to 3D print a soft robotic gripper with high toughness and self‐healing capability. This work demonstrates a simple strategy for the additive manufacturing of tough and self‐healable soft robotic gripper. The resin based on deep eutectic solvents can be rapidly cured to form tough ionogels without chemical crosslinkers by harnessing its intense hydrogen bonding interactions. Furthermore, the ionogels show not only efficient energy‐dissipating behavior, but also rapid self‐recovery.