Novel Approach to Color‐Neutral Transparent Solar Cells: An Organic‐Si Hybrid Achieved by Laser Microhole Drilling

Transparent solar cells (TSCs) hold promise for applications in building‐integrated photovoltaics (BIPVs) and vehicles. However, existing TSCs often have compromised color neutrality and efficiency because of the distinctive colors arising from their photoactive materials. The study proposes a novel fabrication method for TSCs based on Si wafers with the average visible transmittance (AVT) controlled by creating a microhole pattern through a combination of nanosecond laser drilling and subsequent wet etching. Through this ambient‐air process, organic–Si hybrid TSCs are successfully realized by integrating an organic PEDOT:PSS layer onto this structure with a neutral color. The power conversion efficiency (PCE) is adjusted by the fraction of the perforated region, and it attained 6.20% at 30% AVT, 5.37% at 40% AVT, and 4.67% at 50% AVT. In this hybrid TSC approach, the CIE color coordinates are closely aligned with the neutral‐color points (0, 0), resulting in color rendering index (CRI) values exceeding 99. The strategy represents a significant step toward the development of efficient color‐neutral TSCs for transparent solar applications. The study demonstrates PEDOT: PSS‐based organic hybrid transparent Si solar cells by a cost‐effective method, combining nanosecond laser perforation and wet etching under ambient conditions. The devices achieve impressive efficiencies of 6.20%, 5.37%, and 4.67% at transmittances of 30%, 40%, and 50%, respectively, and guarantee optically neutral color, maintaining clarity with a color rendering index of ≈100.