Superbiphilic hierarchical aluminum surfaces for exceptional pool boiling performance

The advancement in high-power electronic devices coupled with the need to ensure reliable and efficient heat dissipation of two-phase cooling systems underscores the urgent necessity for breakthroughs in enhancing boiling performance and especially critical heat flux (CHF) to minimize the risk of system failure. In this field, surfaces with tailored wettability have already demonstrated their potential to enhance boiling heat transfer intensity, while surfaces featuring wickable structures like micropillar arrays have shown significant improvements in CHF. In this study, we investigate the use of aluminium micropillar surfaces with tailored wettability to simultaneously enhance nucleate boiling heat transfer performance and specifically increase of the CHF. We fabricated the micropillar surfaces using a combination of nanosecond laser texturing and chemical etching in hydrochloric acid, while the wettability of selected surfaces was further tailored by application of a fluoroalkyl phosphonic acid and an additional laser texturing step. Three micropillar patterns were tested under pool boiling conditions using saturated twice-distilled water at atmospheric pressure. Importantly, our results revealed that the bottom part of the boiling interface (i.e., the superhydrophilic area) ensured increased liquid supply, while the top parts (i.e., the superhydrophobic area) tend to serve as nucleation sites. When combined, these two effects allowed us to simultaneously improve the CHF and the heat transfer coefficient, resulting in enhancements of up to 113% (2343 kW m−2) and 450% (205 kW m−2 K−1), respectively, compared to the benchmark untreated surface. This research provides a practical and reliable approach to enhancing heat transfer by fabricating hierarchical surfaces, offering potential applications in ultrahigh heat flux thermal technologies.