A Comparative Study on the Substitution of Nonmagnetic Ion T3+ (T = Al, Sc and Y; 0 ≤ × ≤ 0.2) on the Co2Sn1−xTxO4 Spinel Oxides to Investigate the Magnetic Characteristics
Co 2 Sn 1− x T x O 4 (T = Al, Sc, and Y; 0 ≤ x ≤ 0.2) magnetic spinel oxides have been synthesized through solid-state reaction. The XRD pattern displays a single-phase cubic structure with space group Fd3m. Moreover, magnetic susceptibility results show that substituting trivalent non-magnetic io...
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| Veröffentlicht in: | Journal of electronic materials 2024-06, Vol.53 (6), p.2861-2873 |
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| creator | Ali, Wajahat Xinghan, Chen Ashtar, Maalik Hongxia, Yin Razaq, Abdul Younis, Muhammad Zhilong, Zheng Songliu, Yuan |
| description | Co
2
Sn
1−
x
T
x
O
4
(T = Al, Sc, and Y; 0 ≤
x
≤ 0.2) magnetic spinel oxides have been synthesized through solid-state reaction. The XRD pattern displays a single-phase cubic structure with space group Fd3m. Moreover, magnetic susceptibility results show that substituting trivalent non-magnetic ions improves the para-ferrimagnetic transition temperature,
T
C
. Magnetic susceptibility results of direct current (dc) and alternating current (ac) showed that the T
3
+
substitution increased the freezing temperature of the spin-glass state, and was also beneficial to the growth of the spin-glass phase. The apparent magnetic exchange bias effect at low temperatures (
T
|
| doi_str_mv | 10.1007/s11664-024-10998-x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_3053355604</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3053355604</sourcerecordid><originalsourceid>FETCH-LOGICAL-c200t-88d2a90fcc4b0ed72511805bbfe3139382d5a17f6d7a08a4deaa51a03548ea0f3</originalsourceid><addsrcrecordid>eNp9UctuEzEUtRCVCC0_wMoSGxBMudceTxwhFtGIR6RCFgkSrCxnxpNOldip7ammfwBbNmyz4Ce6Tf-kX4JpWrFjdV_ncaVDyFOEYwQYvg6IRZFnwPIMYTSSWf-ADFDkPENZfH1IBsALzATj4hF5HMIZAAqUOCBXY1q69UZ7HdsLQ2exqy-pszSepqFbhNjGLrZp4Rr62dm1XloT24pO0mrOX9Ln89327W47Xr2is4pqW9Nvbyjstjc_fu-217_uGjhmL-5VS8dmFm--_-zn_TSns01rzYpO-7Y2gUZHJ_bCJNuljuYW_-nesjxNX1bR-Dadq3BEDhq9CubJXT0kX96_m5cfs5Pph0k5PskqBhAzKWumR9BUVb4AUw-ZQJQgFovGcOQjLlktNA6boh5qkDqvjdYCNXCRS6Oh4Yfk2V534915l15TZ67zNlkqDoJzIQrIE4rtUZV3IXjTqI1v19pfKgT1NyK1j0iliNRtRKpPJL4nhQS2S-P_Sf-H9Qf75Jv3</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3053355604</pqid></control><display><type>article</type><title>A Comparative Study on the Substitution of Nonmagnetic Ion T3+ (T = Al, Sc and Y; 0 ≤ × ≤ 0.2) on the Co2Sn1−xTxO4 Spinel Oxides to Investigate the Magnetic Characteristics</title><source>SpringerLink Journals - AutoHoldings</source><creator>Ali, Wajahat ; Xinghan, Chen ; Ashtar, Maalik ; Hongxia, Yin ; Razaq, Abdul ; Younis, Muhammad ; Zhilong, Zheng ; Songliu, Yuan</creator><creatorcontrib>Ali, Wajahat ; Xinghan, Chen ; Ashtar, Maalik ; Hongxia, Yin ; Razaq, Abdul ; Younis, Muhammad ; Zhilong, Zheng ; Songliu, Yuan</creatorcontrib><description>Co
2
Sn
1−
x
T
x
O
4
(T = Al, Sc, and Y; 0 ≤
x
≤ 0.2) magnetic spinel oxides have been synthesized through solid-state reaction. The XRD pattern displays a single-phase cubic structure with space group Fd3m. Moreover, magnetic susceptibility results show that substituting trivalent non-magnetic ions improves the para-ferrimagnetic transition temperature,
T
C
. Magnetic susceptibility results of direct current (dc) and alternating current (ac) showed that the T
3
+
substitution increased the freezing temperature of the spin-glass state, and was also beneficial to the growth of the spin-glass phase. The apparent magnetic exchange bias effect at low temperatures (
T
< 20 K) was realized in the Co
2
Sn
1−
x
T
x
O
4
samples using the pinning effect in the spin-glass phase. Due to the magnetic exchange bias effect, the magnetism of the system dramatically increased at low temperatures. Thermal exchange bias results show that the coercivity field (
H
C
) at 10 K increased from 0 for
x
= 0 samples to ~ 2.1, 1.3, and 2.9 kOe for Al-, Sc-, and Y-doped samples, respectively. It can optimize magnetic materials and architectures, improving performance and practicality in magnetic data storage, magnetic sensors, spintronics, and magnetic nanoparticles.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-024-10998-x</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Bias ; Catalysis ; Characterization and Evaluation of Materials ; Chemical synthesis ; Chemistry and Materials Science ; Coercivity ; Comparative studies ; Data storage ; Direct current ; Electronics and Microelectronics ; Electrons ; Exchanging ; Freezing ; Heat treating ; Instrumentation ; Investigations ; Low temperature ; Magnetic materials ; Magnetic permeability ; Magnetic properties ; Magnetism ; Materials Science ; Optical and Electronic Materials ; Original Research Article ; Scandium ; Sensors ; Software ; Solid State Physics ; Spin glasses ; Spinel ; Spintronics ; Substitution reactions ; Temperature ; Transition temperature</subject><ispartof>Journal of electronic materials, 2024-06, Vol.53 (6), p.2861-2873</ispartof><rights>The Minerals, Metals & Materials Society 2024. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c200t-88d2a90fcc4b0ed72511805bbfe3139382d5a17f6d7a08a4deaa51a03548ea0f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11664-024-10998-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11664-024-10998-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Ali, Wajahat</creatorcontrib><creatorcontrib>Xinghan, Chen</creatorcontrib><creatorcontrib>Ashtar, Maalik</creatorcontrib><creatorcontrib>Hongxia, Yin</creatorcontrib><creatorcontrib>Razaq, Abdul</creatorcontrib><creatorcontrib>Younis, Muhammad</creatorcontrib><creatorcontrib>Zhilong, Zheng</creatorcontrib><creatorcontrib>Songliu, Yuan</creatorcontrib><title>A Comparative Study on the Substitution of Nonmagnetic Ion T3+ (T = Al, Sc and Y; 0 ≤ × ≤ 0.2) on the Co2Sn1−xTxO4 Spinel Oxides to Investigate the Magnetic Characteristics</title><title>Journal of electronic materials</title><addtitle>J. Electron. Mater</addtitle><description>Co
2
Sn
1−
x
T
x
O
4
(T = Al, Sc, and Y; 0 ≤
x
≤ 0.2) magnetic spinel oxides have been synthesized through solid-state reaction. The XRD pattern displays a single-phase cubic structure with space group Fd3m. Moreover, magnetic susceptibility results show that substituting trivalent non-magnetic ions improves the para-ferrimagnetic transition temperature,
T
C
. Magnetic susceptibility results of direct current (dc) and alternating current (ac) showed that the T
3
+
substitution increased the freezing temperature of the spin-glass state, and was also beneficial to the growth of the spin-glass phase. The apparent magnetic exchange bias effect at low temperatures (
T
< 20 K) was realized in the Co
2
Sn
1−
x
T
x
O
4
samples using the pinning effect in the spin-glass phase. Due to the magnetic exchange bias effect, the magnetism of the system dramatically increased at low temperatures. Thermal exchange bias results show that the coercivity field (
H
C
) at 10 K increased from 0 for
x
= 0 samples to ~ 2.1, 1.3, and 2.9 kOe for Al-, Sc-, and Y-doped samples, respectively. It can optimize magnetic materials and architectures, improving performance and practicality in magnetic data storage, magnetic sensors, spintronics, and magnetic nanoparticles.</description><subject>Bias</subject><subject>Catalysis</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical synthesis</subject><subject>Chemistry and Materials Science</subject><subject>Coercivity</subject><subject>Comparative studies</subject><subject>Data storage</subject><subject>Direct current</subject><subject>Electronics and Microelectronics</subject><subject>Electrons</subject><subject>Exchanging</subject><subject>Freezing</subject><subject>Heat treating</subject><subject>Instrumentation</subject><subject>Investigations</subject><subject>Low temperature</subject><subject>Magnetic materials</subject><subject>Magnetic permeability</subject><subject>Magnetic properties</subject><subject>Magnetism</subject><subject>Materials Science</subject><subject>Optical and Electronic Materials</subject><subject>Original Research Article</subject><subject>Scandium</subject><subject>Sensors</subject><subject>Software</subject><subject>Solid State Physics</subject><subject>Spin glasses</subject><subject>Spinel</subject><subject>Spintronics</subject><subject>Substitution reactions</subject><subject>Temperature</subject><subject>Transition temperature</subject><issn>0361-5235</issn><issn>1543-186X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9UctuEzEUtRCVCC0_wMoSGxBMudceTxwhFtGIR6RCFgkSrCxnxpNOldip7ammfwBbNmyz4Ce6Tf-kX4JpWrFjdV_ncaVDyFOEYwQYvg6IRZFnwPIMYTSSWf-ADFDkPENZfH1IBsALzATj4hF5HMIZAAqUOCBXY1q69UZ7HdsLQ2exqy-pszSepqFbhNjGLrZp4Rr62dm1XloT24pO0mrOX9Ln89327W47Xr2is4pqW9Nvbyjstjc_fu-217_uGjhmL-5VS8dmFm--_-zn_TSns01rzYpO-7Y2gUZHJ_bCJNuljuYW_-nesjxNX1bR-Dadq3BEDhq9CubJXT0kX96_m5cfs5Pph0k5PskqBhAzKWumR9BUVb4AUw-ZQJQgFovGcOQjLlktNA6boh5qkDqvjdYCNXCRS6Oh4Yfk2V534915l15TZ67zNlkqDoJzIQrIE4rtUZV3IXjTqI1v19pfKgT1NyK1j0iliNRtRKpPJL4nhQS2S-P_Sf-H9Qf75Jv3</recordid><startdate>20240601</startdate><enddate>20240601</enddate><creator>Ali, Wajahat</creator><creator>Xinghan, Chen</creator><creator>Ashtar, Maalik</creator><creator>Hongxia, Yin</creator><creator>Razaq, Abdul</creator><creator>Younis, Muhammad</creator><creator>Zhilong, Zheng</creator><creator>Songliu, Yuan</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20240601</creationdate><title>A Comparative Study on the Substitution of Nonmagnetic Ion T3+ (T = Al, Sc and Y; 0 ≤ × ≤ 0.2) on the Co2Sn1−xTxO4 Spinel Oxides to Investigate the Magnetic Characteristics</title><author>Ali, Wajahat ; Xinghan, Chen ; Ashtar, Maalik ; Hongxia, Yin ; Razaq, Abdul ; Younis, Muhammad ; Zhilong, Zheng ; Songliu, Yuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c200t-88d2a90fcc4b0ed72511805bbfe3139382d5a17f6d7a08a4deaa51a03548ea0f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Bias</topic><topic>Catalysis</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical synthesis</topic><topic>Chemistry and Materials Science</topic><topic>Coercivity</topic><topic>Comparative studies</topic><topic>Data storage</topic><topic>Direct current</topic><topic>Electronics and Microelectronics</topic><topic>Electrons</topic><topic>Exchanging</topic><topic>Freezing</topic><topic>Heat treating</topic><topic>Instrumentation</topic><topic>Investigations</topic><topic>Low temperature</topic><topic>Magnetic materials</topic><topic>Magnetic permeability</topic><topic>Magnetic properties</topic><topic>Magnetism</topic><topic>Materials Science</topic><topic>Optical and Electronic Materials</topic><topic>Original Research Article</topic><topic>Scandium</topic><topic>Sensors</topic><topic>Software</topic><topic>Solid State Physics</topic><topic>Spin glasses</topic><topic>Spinel</topic><topic>Spintronics</topic><topic>Substitution reactions</topic><topic>Temperature</topic><topic>Transition temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ali, Wajahat</creatorcontrib><creatorcontrib>Xinghan, Chen</creatorcontrib><creatorcontrib>Ashtar, Maalik</creatorcontrib><creatorcontrib>Hongxia, Yin</creatorcontrib><creatorcontrib>Razaq, Abdul</creatorcontrib><creatorcontrib>Younis, Muhammad</creatorcontrib><creatorcontrib>Zhilong, Zheng</creatorcontrib><creatorcontrib>Songliu, Yuan</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of electronic materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ali, Wajahat</au><au>Xinghan, Chen</au><au>Ashtar, Maalik</au><au>Hongxia, Yin</au><au>Razaq, Abdul</au><au>Younis, Muhammad</au><au>Zhilong, Zheng</au><au>Songliu, Yuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Comparative Study on the Substitution of Nonmagnetic Ion T3+ (T = Al, Sc and Y; 0 ≤ × ≤ 0.2) on the Co2Sn1−xTxO4 Spinel Oxides to Investigate the Magnetic Characteristics</atitle><jtitle>Journal of electronic materials</jtitle><stitle>J. Electron. Mater</stitle><date>2024-06-01</date><risdate>2024</risdate><volume>53</volume><issue>6</issue><spage>2861</spage><epage>2873</epage><pages>2861-2873</pages><issn>0361-5235</issn><eissn>1543-186X</eissn><abstract>Co
2
Sn
1−
x
T
x
O
4
(T = Al, Sc, and Y; 0 ≤
x
≤ 0.2) magnetic spinel oxides have been synthesized through solid-state reaction. The XRD pattern displays a single-phase cubic structure with space group Fd3m. Moreover, magnetic susceptibility results show that substituting trivalent non-magnetic ions improves the para-ferrimagnetic transition temperature,
T
C
. Magnetic susceptibility results of direct current (dc) and alternating current (ac) showed that the T
3
+
substitution increased the freezing temperature of the spin-glass state, and was also beneficial to the growth of the spin-glass phase. The apparent magnetic exchange bias effect at low temperatures (
T
< 20 K) was realized in the Co
2
Sn
1−
x
T
x
O
4
samples using the pinning effect in the spin-glass phase. Due to the magnetic exchange bias effect, the magnetism of the system dramatically increased at low temperatures. Thermal exchange bias results show that the coercivity field (
H
C
) at 10 K increased from 0 for
x
= 0 samples to ~ 2.1, 1.3, and 2.9 kOe for Al-, Sc-, and Y-doped samples, respectively. It can optimize magnetic materials and architectures, improving performance and practicality in magnetic data storage, magnetic sensors, spintronics, and magnetic nanoparticles.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11664-024-10998-x</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0361-5235 |
| ispartof | Journal of electronic materials, 2024-06, Vol.53 (6), p.2861-2873 |
| issn | 0361-5235 1543-186X |
| language | eng |
| recordid | cdi_proquest_journals_3053355604 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Bias Catalysis Characterization and Evaluation of Materials Chemical synthesis Chemistry and Materials Science Coercivity Comparative studies Data storage Direct current Electronics and Microelectronics Electrons Exchanging Freezing Heat treating Instrumentation Investigations Low temperature Magnetic materials Magnetic permeability Magnetic properties Magnetism Materials Science Optical and Electronic Materials Original Research Article Scandium Sensors Software Solid State Physics Spin glasses Spinel Spintronics Substitution reactions Temperature Transition temperature |
| title | A Comparative Study on the Substitution of Nonmagnetic Ion T3+ (T = Al, Sc and Y; 0 ≤ × ≤ 0.2) on the Co2Sn1−xTxO4 Spinel Oxides to Investigate the Magnetic Characteristics |
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