A Comparative Study on the Substitution of Nonmagnetic Ion T3+ (T = Al, Sc and Y; 0 ≤ × ≤ 0.2) on the Co2Sn1−xTxO4 Spinel Oxides to Investigate the Magnetic Characteristics
Co 2 Sn 1− x T x O 4 (T = Al, Sc, and Y; 0 ≤ x ≤ 0.2) magnetic spinel oxides have been synthesized through solid-state reaction. The XRD pattern displays a single-phase cubic structure with space group Fd3m. Moreover, magnetic susceptibility results show that substituting trivalent non-magnetic io...
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Veröffentlicht in: | Journal of electronic materials 2024-06, Vol.53 (6), p.2861-2873 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | Co
2
Sn
1−
x
T
x
O
4
(T = Al, Sc, and Y; 0 ≤
x
≤ 0.2) magnetic spinel oxides have been synthesized through solid-state reaction. The XRD pattern displays a single-phase cubic structure with space group Fd3m. Moreover, magnetic susceptibility results show that substituting trivalent non-magnetic ions improves the para-ferrimagnetic transition temperature,
T
C
. Magnetic susceptibility results of direct current (dc) and alternating current (ac) showed that the T
3
+
substitution increased the freezing temperature of the spin-glass state, and was also beneficial to the growth of the spin-glass phase. The apparent magnetic exchange bias effect at low temperatures (
T
|
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ISSN: | 0361-5235 1543-186X |
DOI: | 10.1007/s11664-024-10998-x |