Origin and tectonic setting of low-Si alkaline magma
Despite of the relatively rare occurrence of alkaline igneous rocks on Earth, they are the most diverse group of igneous rocks due to variations in their mineral assemblages and geochemical compositions. Alkaline igneous rocks are generally characterized by Si undersaturation, and K-Na (and in some...
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Veröffentlicht in: | Science China. Earth sciences 2024-05, Vol.67 (5), p.1417-1435 |
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Zusammenfassung: | Despite of the relatively rare occurrence of alkaline igneous rocks on Earth, they are the most diverse group of igneous rocks due to variations in their mineral assemblages and geochemical compositions. Alkaline igneous rocks are generally characterized by Si undersaturation, and K-Na (and in some cases C) enrichment. Although there is no unified alkaline igneous rock classification scheme, diagrams such as total alkalis-SiO
2
or K
2
O-SiO
2
can be used to classify alkaline igneous rocks. The origins of silica-saturated alkaline rocks (SiO
2
>52 wt.%) are relatively complex because multiple episodes of magmatism are often involved, therefore most studies have focused on the origins of silica-undersaturated alkaline magmas. Numerous experimental petrological studies have been conducted in the past few decades. Initially, it was considered that enrichment of trace elements was only achieved by low-degree partial melting of mantle peridotite, but the experimental melts could not reproduce the geochemical composition of natural alkaline igneous rocks. Subsequent studies have focused on carbonate-bearing eclogites that represent the average component of subducted oceanic crust. Although experimental studies indicate that silica-undersaturated and alkali-oversaturated melts can be generated from eclogites, some studies have considered that natural silica-undersaturated alkaline igneous rocks are the result of multi-stage source enrichment by incompatible elements. Low-degree partial melts of the mantle can be emplaced in the lithospheric mantle, forming veins consisting of phlogopite, amphibole, and pyroxene. Melting experiments including these components show that the produced melts better reproduce the naturally occurring silica-undersaturated alkaline magmas. Silica-deficient alkaline igneous rocks occur in various tectonic settings. Those in intraplate and divergent settings (i.e., mainly continental rifts) normally involve contributions from recycled components such as subducted slabs at the mantle transition zone (MTZ) or metasomatized lithospheric mantle. At convergent plate boundaries, silica-undersaturated alkaline magmas can be derived by the melting of mélange or the focused breakdown of phlogopite at back-arc depths. We compiled global data for alkaline igneous rocks and discovered that silica-undersaturated alkaline igneous rocks in continental collisional zones are K-rich and differ from those from other tectonic settings. We suggest that subducte |
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ISSN: | 1674-7313 1869-1897 |
DOI: | 10.1007/s11430-023-1269-6 |