Silver‐Catalyzed Decarboxylative Acylfluorination of Two Alkenes with Ketonic Acids

Silver‐Catalyzed Decarboxylative Acylfluorination of Two Alkenes with Ketonic Acids

An acylative fluorination of two different alkenes is developed, assisted by the interaction of silver catalyst and Selectflour. Various α‐ketonic acids can be decarboxylated to form acyl radicals at 35 °C, sequentially add to the electron‐deficient and electron‐ rich alkenes to provide the benzyl f...

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Veröffentlicht in:Advanced synthesis & catalysis 2024-04, Vol.366 (7), p.1643-1648
Hauptverfasser: Liu, Ren‐Xiang, Wang, Wei, Yang, Luo
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Fluorination
Functional groups
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Zusammenfassung:An acylative fluorination of two different alkenes is developed, assisted by the interaction of silver catalyst and Selectflour. Various α‐ketonic acids can be decarboxylated to form acyl radicals at 35 °C, sequentially add to the electron‐deficient and electron‐ rich alkenes to provide the benzyl fluorinated compounds containing diversified functional groups.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202301256