The Use of Calcium Carbide for Cyclopentenone Ring Construction

The Use of Calcium Carbide for Cyclopentenone Ring Construction

Calcium carbide can be used for in situ generation of acetylene. This communication presents the synthetic approach to 3a,4,5,6,7,7a-hexahydro-1 H -4,7-methanoinden-1-one involving calcium carbide, norbornene, and dicobalt octacarbonyl. The latter acts both as a catalyst and a source of CO for the c...

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Veröffentlicht in:Russian journal of general chemistry 2024, Vol.94 (1), p.45-48
Hauptverfasser: Ledovskaya, M. S., Voronin, V. V.
Format: Artikel
Sprache:eng
Schlagworte:
Acetylene
Calcium
Carbides
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Zusammenfassung:Calcium carbide can be used for in situ generation of acetylene. This communication presents the synthetic approach to 3a,4,5,6,7,7a-hexahydro-1 H -4,7-methanoinden-1-one involving calcium carbide, norbornene, and dicobalt octacarbonyl. The latter acts both as a catalyst and a source of CO for the construction of the cyclopentenone ring.
ISSN:1070-3632
1608-3350
DOI:10.1134/S107036322401002X