Converting Commercial Zn Foils into Single (002)‐Textured Zn with Millimeter‐Sized Grains for Highly Reversible Aqueous Zinc Batteries

Rechargeable aqueous zinc batteries are promising but hindered by unfavorable dendrite growth and side reactions on zinc anodes. In this study, we demonstrate a fast melting‐solidification approach for effectively converting commercial Zn foils into single (002)‐textured Zn featuring millimeter‐sized grains. The melting process eliminates initial texture, residual stress, and grain size variations in diverse commercial Zn foils, guaranteeing the uniformity of commercial Zn foils into single (002)‐textured Zn. The single (002)‐texture ensures large‐scale epitaxial and dense Zn deposition, while the reduction in grain boundaries significantly minimizes intergranular reactions. These features enable large grain single (002)‐textured Zn shows planar and dense Zn deposition under harsh conditions (100 mA cm−2, 100 mAh cm−2), impressive reversibility in Zn||Zn symmetric cell (3280 h under 1 mA cm−2, 830 h under 10 mAh cm−2), and long cycling stability over 180 h with a high depth of discharge value of 75 %. This study successfully addresses the issue of uncontrollable texture formation in Zn foils following routine annealing treatments with temperatures below the Zn melting point. The findings of this study establish a highly efficient strategy for fabricating highly reversible single (002)‐textured Zn anodes. A simple and fast melting‐solidification approach was developed to effectively convert commercial Zn foils into single (002)‐textured Zinc with millimeter‐sized (eye‐visible) grains. The single (002) texture and huge grain features ensure large‐scale epitaxial Zn deposition and significantly minimize the intergranular reactions, resulting in impressive reversibility of Zn metal anode in both Zn||Zn symmetric cells and full cells.