Reversible complexation mediated polymerization (RCMP) starting with a complex of iodine with organic salt and thermal initiators

Reversible complexation mediated polymerization (RCMP) starting with a complex of iodine with organic salt and thermal initiators

Herein, we developed a reversible complexation mediated polymerization (RCMP) starting with a complex of iodine and organic salt as a deactivator and a thermal initiator for continuous regeneration of the organic salt activator. This novel polymerization method can be called as initiators for contin...

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Veröffentlicht in:Journal of polymer research 2024-04, Vol.31 (4), Article 123
Hauptverfasser: Liu, Yunhe, Fang, Xiya, Feng, Zongze, Zhang, Xiaotao, Wang, Honggen, Shi, Yan
Format: Artikel
Sprache:eng
Schlagworte:
Block copolymers
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Complexation
Copolymerization
Deactivation
Industrial Chemistry/Chemical Engineering
Initiators
Iodine
Organic salts
Original Paper
Polymer Sciences
Polymerization
Polymethyl methacrylate
Regeneration
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Zusammenfassung:Herein, we developed a reversible complexation mediated polymerization (RCMP) starting with a complex of iodine and organic salt as a deactivator and a thermal initiator for continuous regeneration of the organic salt activator. This novel polymerization method can be called as initiators for continuous activator regeneration (ICAR) RCMP, as inspired by the denomination of ICAR ATRP. The synthesis of poly (methyl methacrylate) (PMMA) ( M w / M n  
ISSN:1022-9760
1572-8935
DOI:10.1007/s10965-024-03948-y