Magnetic Properties and Magnetocaloric Effect in Tb2FeCrO6 Double Perovskite Oxide

In this work, we fabricated a polycrystalline Tb 2 FeCrO 6 double perovskite (DP) oxide by a solid-state reaction method and determined its structural, magnetic, and magnetocaloric (MC) properties. The Tb 2 FeCrO 6 DP oxide was found to crystallize in a DP-type structure with the Pbnm space group an...

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Veröffentlicht in:Journal of electronic materials 2024-05, Vol.53 (5), p.2302-2308
Hauptverfasser: Huang, Silu, Lin, Junli, Shu, Yongyun, Zhang, Yikun
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Shu, Yongyun
Zhang, Yikun
description In this work, we fabricated a polycrystalline Tb 2 FeCrO 6 double perovskite (DP) oxide by a solid-state reaction method and determined its structural, magnetic, and magnetocaloric (MC) properties. The Tb 2 FeCrO 6 DP oxide was found to crystallize in a DP-type structure with the Pbnm space group and to undergo a paramagnetic-to-antiferromagnetic transition at a temperature of ~ 8.5 K. A large low-temperature MC effect was observed in the Tb 2 FeCrO 6 DP oxide. The MC parameters in terms of maximum magnetic entropy changes, temperature-averaged entropy change (5 K), and relative cooling power for Tb 2 FeCrO 6 DP oxide under a magnetic field change of 0–7 T were 12.9 J/kg K, 12.7 J/kg K, and 341.4 J/kg, respectively. These parameters were consistent with similarly high levels in recently updated MC materials, making the material a suitable candidate for low-temperature magnetic cooling applications.
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subjects Antiferromagnetism
Characterization and Evaluation of Materials
Chemistry and Materials Science
Cooling
Electronics and Microelectronics
Entropy
Instrumentation
Low temperature
Magnetic cooling
Magnetic fields
Magnetic properties
Materials Science
Optical and Electronic Materials
Original Research Article
Parameters
Perovskites
Phase transitions
Scanning electron microscopy
Solid State Physics
title Magnetic Properties and Magnetocaloric Effect in Tb2FeCrO6 Double Perovskite Oxide
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