Magnetic Properties and Magnetocaloric Effect in Tb2FeCrO6 Double Perovskite Oxide
In this work, we fabricated a polycrystalline Tb 2 FeCrO 6 double perovskite (DP) oxide by a solid-state reaction method and determined its structural, magnetic, and magnetocaloric (MC) properties. The Tb 2 FeCrO 6 DP oxide was found to crystallize in a DP-type structure with the Pbnm space group an...
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Veröffentlicht in: | Journal of electronic materials 2024-05, Vol.53 (5), p.2302-2308 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In this work, we fabricated a polycrystalline Tb
2
FeCrO
6
double perovskite (DP) oxide by a solid-state reaction method and determined its structural, magnetic, and magnetocaloric (MC) properties. The Tb
2
FeCrO
6
DP oxide was found to crystallize in a DP-type structure with the
Pbnm
space group and to undergo a paramagnetic-to-antiferromagnetic transition at a temperature of ~ 8.5 K. A large low-temperature MC effect was observed in the Tb
2
FeCrO
6
DP oxide. The MC parameters in terms of maximum magnetic entropy changes, temperature-averaged entropy change (5 K), and relative cooling power for Tb
2
FeCrO
6
DP oxide under a magnetic field change of 0–7 T were 12.9 J/kg K, 12.7 J/kg K, and 341.4 J/kg, respectively. These parameters were consistent with similarly high levels in recently updated MC materials, making the material a suitable candidate for low-temperature magnetic cooling applications. |
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ISSN: | 0361-5235 1543-186X |
DOI: | 10.1007/s11664-024-10993-2 |