Magnetic Properties and Magnetocaloric Effect in Tb2FeCrO6 Double Perovskite Oxide

In this work, we fabricated a polycrystalline Tb 2 FeCrO 6 double perovskite (DP) oxide by a solid-state reaction method and determined its structural, magnetic, and magnetocaloric (MC) properties. The Tb 2 FeCrO 6 DP oxide was found to crystallize in a DP-type structure with the Pbnm space group an...

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Veröffentlicht in:Journal of electronic materials 2024-05, Vol.53 (5), p.2302-2308
Hauptverfasser: Huang, Silu, Lin, Junli, Shu, Yongyun, Zhang, Yikun
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Sprache:eng
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Zusammenfassung:In this work, we fabricated a polycrystalline Tb 2 FeCrO 6 double perovskite (DP) oxide by a solid-state reaction method and determined its structural, magnetic, and magnetocaloric (MC) properties. The Tb 2 FeCrO 6 DP oxide was found to crystallize in a DP-type structure with the Pbnm space group and to undergo a paramagnetic-to-antiferromagnetic transition at a temperature of ~ 8.5 K. A large low-temperature MC effect was observed in the Tb 2 FeCrO 6 DP oxide. The MC parameters in terms of maximum magnetic entropy changes, temperature-averaged entropy change (5 K), and relative cooling power for Tb 2 FeCrO 6 DP oxide under a magnetic field change of 0–7 T were 12.9 J/kg K, 12.7 J/kg K, and 341.4 J/kg, respectively. These parameters were consistent with similarly high levels in recently updated MC materials, making the material a suitable candidate for low-temperature magnetic cooling applications.
ISSN:0361-5235
1543-186X
DOI:10.1007/s11664-024-10993-2