Optical Properties of Ferroelectric Films HfxZryO2 and La:HfxZryO2 according to Ellipsometry Data

Recently ferroelectric properties have been found in hafnia-based nanosized films. Such films are of the utmost interest for development of a universal memory, which combines the advantages of random access memory and flash memory. The paper studies optical properties of hafnia-zirconium oxide films...

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Veröffentlicht in:Optics and spectroscopy 2023-07, Vol.131 (7), p.550-553
Hauptverfasser: Kruchinin, V. N., Spesivtsev, E. V., Rykhlitsky, C. V., Gritsenko, V. A., Mehmood, F., Mikolajick, T., Schroeder, U.
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Sprache:eng
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Zusammenfassung:Recently ferroelectric properties have been found in hafnia-based nanosized films. Such films are of the utmost interest for development of a universal memory, which combines the advantages of random access memory and flash memory. The paper studies optical properties of hafnia-zirconium oxide films H-f x Zr y O 2 and lanthanum-alloyed hafnia-zirconium oxide films La:Hf x Zr y O 2 . Fluctuations of thickness in Hf x Zr y O 2 do not exceed 3.5%, fluctuations of thickness in La:Hf x Zr y O 2 films—3.2%. Optical properties are analyzed based on effective-medium theory. According to effective-medium theory data, Hf x Zr y O 2 films contain 46% HfO 2 , 54% ZrO 2 , La:Hf x Zr y O 2 films contain 47.5% HfO 2 , 52.4% ZrO 2 , 2.5% La 2 O 3 .
ISSN:0030-400X
1562-6911
DOI:10.1134/S0030400X23050107